一种全钒液流电池用高稳定性电解液及其制备方法

By using polar solvents and pyrrole as stabilizers in vanadium redox flow batteries, combined with a mixed acid system and inorganic additives, the problems of electrolyte solidification and vanadium ion precipitation and crystallization were solved, enabling stable operation and efficient energy storage of the battery in low-temperature environments.

CN121983629BActive Publication Date: 2026-07-17HUNAN YINFENG NEW ENERGY CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HUNAN YINFENG NEW ENERGY CO LTD
Filing Date
2026-04-07
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Vanadium redox flow batteries are prone to electrolyte solidification and vanadium ion precipitation and crystallization in sub-zero temperature environments, which affects battery performance and may cause blockage, limiting their application in low-temperature environments.

Method used

Polar solvents and pyrrole are used as stabilizers. The freezing point of the electrolyte is lowered by the interaction of polar molecules with hydrogen bonds. The viscosity of the electrolyte and the dispersion of vanadium ions are improved by the solubility of pyrrole and the formation of polymers. Combined with mixed acid system and inorganic additives, the dissolution balance and conductivity of vanadium ions are maintained.

Benefits of technology

It effectively broadens the normal operating temperature range of the vanadium redox flow battery, improves the battery's low-temperature stability and charge/discharge speed, enhances the battery's energy storage efficiency and cycle performance, and ensures that the electrolyte remains free from precipitation or solidification for more than 60 days at -20℃.

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Abstract

本申请涉及液流电池领域,具体涉及一种全钒液流电池用高稳定性电解液及其制备方法。一种全钒液流电池用高稳定性电解液,包括电解液原液和稳定剂,所述稳定剂包括极性溶剂和吡咯,所述极性溶剂包括丙酮和N‑甲基吡咯烷酮中的至少一种;所述电解液原液中钒浓度为2.0~4.5mol / L,硫酸根浓度为2~4mol / L,氯离子浓度为3.2~5.8mol / L,所述电解液原液中钒的价态为2价、3价、4价、5价或其中间价态。本申请中以极性溶剂和吡咯作为稳定剂,有效克服了全钒液流电池在零下温度环境中容易出现电解液凝固和钒离子析出结晶的问题,拓宽了全钒液流电池正常运行温域。
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