电极及其制备方法、提锂方法

By calcining lithium manganese oxide and terbium salts and electrochemically delithitoylating them to form electrodes with lithium vacancies, the problems of cycle stability and selectivity of lithium manganese oxide electrodes in complex systems were solved, and efficient extraction of lithium resources was achieved.

CN122000280BActive Publication Date: 2026-07-17HANGZHOU INST FOR ADVANCED STUDY UCAS

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HANGZHOU INST FOR ADVANCED STUDY UCAS
Filing Date
2026-04-09
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Traditional lithium manganese oxide electrodes suffer from poor cycle stability and insufficient selectivity for lithium ions during lithium ore processing, especially in high-salt, multi-ion coexistence systems, making it difficult to efficiently extract lithium resources.

Method used

By calcining lithium manganese oxide and terbium salt, LiMn2-xTbXO4 active material is formed. Then, a voltage is applied in the delithiation three-electrode system to form a second active material with lithium vacancies, which suppresses the Jahn-Teller effect and manganese dissolution, and improves cycle stability and selectivity.

Benefits of technology

It significantly improves the cycling stability and lithium-ion selectivity of the electrode, enabling efficient extraction of lithium resources in complex systems, and is suitable for complex systems such as lithium slag leachate and salt lake brine.

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Abstract

本申请涉及电化学技术领域,尤其涉及一种电极及其制备方法、提锂方法。电极的制备方法包括以下步骤:对锰酸锂和铽盐进行煅烧处理,以得到第一活性物质,所述第一活性物质为LiMn2‑XTbXO4,0.005≤X≤0.02;将第一活性物质、导电剂、粘结剂和溶剂进行搅拌,以得到电极浆料;将所述电极浆料覆盖在石墨片上并烘干,得到预电极;在脱锂三电极体系中,以所述预电极为第一工作电极,对所述第一工作电极施加电压,以使所述第一活性物质中的锂离子脱出形成具有锂空位的第二活性物质,得到所述电极。本申请实施例的方法工艺可控性强且简单,获得的电极中的第二活性物质的循环稳定性和对Li+的选择性均较优。
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