一种互连结构及其制备方法

By using an organic hydrophobic layer and nitrogen and hydrogen free radicals excited by metastable particles in copper metal vias, a dense tantalum layer is formed as a diffusion barrier layer, which solves the problems of poor interfacial affinity and increased contact resistance caused by thinning of the diffusion barrier layer, and achieves lower contact resistance and RC delay.

CN122003142BActive Publication Date: 2026-07-17SHANGHAI BANGXIN SEMI TECHNOLOGY CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHANGHAI BANGXIN SEMI TECHNOLOGY CO LTD
Filing Date
2026-04-07
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

As linewidth shrinks, the thinning of the diffusion barrier layer in copper vias leads to poor interfacial affinity, resulting in film pits and peeling defects, which in turn increases contact resistance and RC delay. Existing TaN and Ta combined diffusion barrier layers are difficult to further thin.

Method used

An organic hydrophobic monolayer is formed at the bottom of the through-hole using a vapor-phase self-assembly process. The sidewalls and bottom surfaces are then treated with nitrogen and hydrogen free radicals excited by metastable particles to improve the adhesion of the low dielectric constant material and its ability to block interfacial diffusion, thus forming a dense tantalum layer as a single diffusion barrier layer.

Benefits of technology

It enhances the deposition quality of the tantalum layer, reduces contact resistance and RC delay, meets the low resistance and high reliability requirements of advanced nodes, avoids the problem of increased contact resistance in existing processes, and achieves a lower diffusion barrier layer thickness.

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Abstract

本申请公开了一种互连结构及其制备方法,包括:在衬底上形成位于第一介电层中的第一金属层;在第一介电层上形成低介电常数材料的第二介电层,在第二介电层上形成连接第一金属层的通孔;使用气相自组装工艺,在通孔底部的第一金属层上形成单分子层的有机疏水层;对通孔的侧壁进行第一处理,以提高低介电常数材料表面的粘附性和阻挡界面扩散能力;在通孔的侧壁上形成钽层,并抑制钽层形成在有机疏水层上;去除有机疏水层,在钽层以内的通孔中填充与第一金属层电连接的第二金属层。本申请能够有效降低扩散阻挡层的阻值在整个通孔中的阻值的比重,实现更低阻值和互连稳定性,很好满足了先进节点的技术要求。
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