一种用于裂解富碳天然气制备类石墨碳的复合催化剂及其应用方法

By using a composite catalyst composed of a low-melting-point metal matrix, reversible valence metal compounds, and metal halide salts, carbon-rich natural gas can be cracked in situ within the wellbore. This solves the problems of easy catalyst deactivation and uncontrollable carbon structure, and achieves efficient generation of highly ordered graphite-like carbon and highly selective hydrogen.

CN122006756BActive Publication Date: 2026-07-17SOUTHWEST PETROLEUM UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SOUTHWEST PETROLEUM UNIV
Filing Date
2026-04-15
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing catalysts are prone to deactivation under high temperature and pressure, making it difficult to control the preparation of graphite-like carbon structures. Furthermore, they lack selectivity in complex well environments and are prone to side reactions. Traditional molten metal catalysts are easily oxidized and deactivated in the presence of carbon dioxide.

Method used

A composite catalyst consisting of a low-melting-point metal matrix, reversible valence metal compounds, and metal halide or carbonate is used to in-situ crack carbon-rich natural gas in the wellbore through multiphase synergy, thereby creating a micro-electrochemical reaction environment and promoting the generation of graphite-like carbon.

Benefits of technology

Highly ordered graphite-like carbon is stably generated under high temperature and high pressure conditions in wellbore, improving hydrogen selectivity, suppressing side reactions, and increasing the added value of the product.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明公开了一种用于裂解富碳天然气制备类石墨碳的复合催化剂及其应用方法,属于催化剂材料技术领域。该复合催化剂由金属基体、催化诱导相和界面调控相组成。催化诱导相为可逆价态金属化合物,界面调控相选自金属卤盐或金属碳酸盐中的至少一种。将金属基体在惰性气氛下加热至熔融,然后加入催化诱导相,均匀分散后再加入界面调控相,混合均匀后冷却得到复合催化剂。应用方法:在井筒目标产层位置布置耐高温密封反应段,反应段内填充复合催化剂;加热使复合催化剂转变为熔融态,然后将富碳天然气导入反应段,使富碳天然气与熔融态催化剂充分接触发生裂解反应。本发明的复合催化剂克服了传统催化剂易失活、碳结构不可控、副反应多等问题。
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