一种电容器用多层共挤聚丙烯复合膜及其制备方法

By using an ABA three-layer co-extrusion structure and modified boron nitride, the problems of reduced breakdown electric field strength and insufficient flame retardancy of polypropylene films at high temperatures were solved, achieving a comprehensive improvement in high dielectric strength, high breakdown strength, and flame retardancy.

CN122008665BActive Publication Date: 2026-07-17扬州博恒新能源材料科技有限公司

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
扬州博恒新能源材料科技有限公司
Filing Date
2026-04-15
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing polypropylene films suffer from reduced breakdown electric field strength and difficulty in increasing dielectric constant under high-temperature conditions, and their flame retardant properties are insufficient, making it difficult to simultaneously meet the requirements of high dielectric, high breakdown, and flame retardancy.

Method used

A multilayer co-extruded polypropylene composite film with an ABA three-layer co-extrusion structure was prepared by mechanically exfoliating and surface modifying boron nitride to prepare BN@SiO2-NH2 flame retardant, which was then premixed with MAH-g-PP to form chemical bonds. Combined with the dispersion of alumina in the B layer, the performance of each layer was optimized.

Benefits of technology

It achieves improved breakdown strength, dielectric properties, and flame retardancy under high-temperature conditions, avoids agglomeration of functional fillers, and improves limiting oxygen index and interfacial bonding strength.

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Abstract

本案涉及电容膜技术领域,具体为电容器用多层共挤聚丙烯复合膜及其制备方法,复合膜为ABA三层共挤出结构;A层含改性阻燃剂,B层原料含BN@SiO2‑NH2及MAH‑g‑PP;改性阻燃剂是将BN@SiO2‑NH2与甲基丙烯酸缩水甘油酯、不饱和磷氮阻燃剂进行聚合反应而得;BN@SiO2‑NH2是将机械剥离的BN与正硅酸乙酯水解制得BN@SiO2,最后与硅烷偶联剂回流接枝制得BN@SiO2‑NH2。通过对BN材料的改性,制得高击穿强度的BN@SiO2‑NH2,对其改性后分别置于AB层中,通过共挤模头制得了ABA三层复合膜,避免功能填料相互干扰,各层性能独立优化,实现阻燃性、介电性、击穿强度的协同提升。
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