一种基于球形介孔构建的一维介孔氧化铋纳米棒及其制备方法

By constructing spherical mesoporous structures of one-dimensional bismuth oxide nanorods using the block copolymer single micelle method, the problem of preparing interconnected mesoporous bismuth oxide in existing technologies has been solved, thereby improving material properties and expanding applications.

CN122010174BActive Publication Date: 2026-07-17INNER MONGOLIA UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
INNER MONGOLIA UNIVERSITY
Filing Date
2026-04-13
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies make it difficult to prepare bismuth oxide materials that possess both one-dimensional morphology and an internally interconnected spherical mesoporous structure, thus limiting their application in high-efficiency catalysis and energy storage.

Method used

By using block copolymer micelles as soft templates and precisely controlling the assembly process of the precursor and micelles as well as the heat treatment conditions, a uniform and interconnected spherical mesoporous structure was constructed in one-dimensional bismuth oxide nanorods.

Benefits of technology

The specific surface area and carrier transport velocity of bismuth oxide nanorods were significantly improved, expanding their application range in photoelectrocatalysis, energy storage and other fields, and exhibiting higher catalytic activity and longer cycle life.

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Abstract

本发明公开了一种基于球形介孔构建的一维介孔氧化铋纳米棒及其制备方法,属于一维介孔材料合成技术领域,该方法采用嵌段共聚物单胶束为软模板,通过精确调控胶束与前驱体的组装过程,结合热处理工艺,成功制备出兼具一维棒状形貌和内部贯通球形介孔结构的氧化铋纳米棒。具体步骤包括:制备嵌段共聚物单胶束溶液;将其与铋前驱体溶液混合,在还原剂作用下形成氧化铋@胶束复合前驱体;再经焙烧去除模板,得到一维介孔氧化铋纳米棒。该材料具有球形介孔孔径可调、比表面积大、孔道贯通性好的特点,在光催化CO2还原等反应中表现出高活性、高选择性和良好的循环稳定性,适用于催化、储能及传感等领域。
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