一种四氧化三锰材料及其制备方法与应用

By preparing a sunflower-like structure of manganese tetroxide material, the problem of structural instability of lithium manganese oxide cathode material at high temperature was solved, achieving efficient lithium-ion transport and stable electrochemical reaction, and improving the high-temperature cycling performance of lithium manganese oxide cathode material.

CN122010184BActive Publication Date: 2026-07-17XIANGTAN ELECTROCHEMICAL SCI CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
XIANGTAN ELECTROCHEMICAL SCI CO LTD
Filing Date
2026-04-10
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing manganese tetroxide materials suffer from manganese dissolution and lattice distortion in lithium manganese oxide cathode materials, leading to structural instability and severe capacity decay, especially under high temperature conditions.

Method used

To prepare a sunflower-like structure of manganese tetroxide material, by controlling the amount of oxidant, pH value and complexing agent concentration, the internal structure of manganese tetroxide particles is assembled from radially arranged plate-like or columnar primary grains to form an ordered structure, thereby enhancing structural stability and lithium ion diffusion pathway.

Benefits of technology

It significantly improves the high-temperature cycling performance of lithium manganese oxide cathode materials, reduces manganese ion dissolution, alleviates capacity decay, and improves lithium ion transport rate and material stability.

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Abstract

本申请提供一种四氧化三锰材料及其制备方法与应用,属于电池材料技术领域。所述四氧化三锰材料具有类向日葵状结构,所述类向日葵状结构是指:四氧化三锰颗粒内部由径向排列的片状或柱状一次晶粒有序组装而成,在颗粒截面呈现由中心向外辐射的类向日葵状形貌。本发明提供的类向日葵状结构的四氧化三锰在常温与高温下都可以维持较优异的容量保持率,为高性能锂离子电池的发展提供了有力的材料支撑。
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