基于量子隧穿效应的单颗粒纳米催化剂检测系统和方法

By combining quantum tunneling effect and functionalized layer, the problems of low signal-to-noise ratio and insufficient fidelity in the detection of nanocatalysts in the prior art are solved, and high sensitivity and multi-dimensional characterization of individual nanocatalysts are achieved.

CN122016944BActive Publication Date: 2026-07-17ZHEJIANG UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
ZHEJIANG UNIV
Filing Date
2026-04-13
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies are insufficient for the high-precision detection of the physical properties and catalytic activity of individual nanocatalysts, especially for small-sized or low-activity nanocatalysts, and suffer from high background noise and low signal-to-noise ratio.

Method used

By employing a nano-gap electrode based on the quantum tunneling effect, combined with a functionalized layer and gate potential modulation, in-situ detection of single-particle nanocatalysts is achieved, and their physical properties and catalytic reaction information are obtained through tunneling current.

Benefits of technology

It achieves high-sensitivity detection of small-sized and low-activity nanocatalysts, improves the signal-to-noise ratio, ensures the fidelity of single-particle events, and simultaneously acquires multi-dimensional information about nanocatalysts.

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Abstract

本发明提供了一种基于量子隧穿效应的单颗粒纳米催化剂检测系统、检测方法和应用。通过构建亚5纳米间隙的量子隧穿电极作为传感核心,并在隧穿电极表面修饰功能化层,并结合门电位调控单颗粒纳米催化剂的催化反应,形成“电导‑电化学”信号联合表征策略,能够以极高的信噪比实现对单个纳米颗粒的原位捕获与识别,同步获取其物理属性与动态催化反应信息,从而在单分子层面为纳米催化剂的精准、全面表征提供一种全新的技术方案。
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