一种磷碳负极水系浆料及其制备方法

By generating fast lithium phosphate conductors in situ on the surface of phosphorus-carbon materials and using acid-resistant PAA binders, the problem of binder deactivation caused by oxidation of phosphorus-carbon anode materials during aqueous homogenization was solved, achieving stable slurry and excellent electrochemical performance.

CN122025643BActive Publication Date: 2026-07-17HEFEI GUOXUAN KEHONG NEW ENERGY TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HEFEI GUOXUAN KEHONG NEW ENERGY TECH CO LTD
Filing Date
2026-04-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Phosphorus-carbon anode materials are prone to oxidation during aqueous homogenization, leading to problems such as binder deactivation, electrode cracking, and foil detachment, which limits their industrial application.

Method used

By adopting a process sequence of first adding a conductive agent and stirring, followed by adding an alkaline lithium salt, a fast lithium phosphate conductor is generated in situ on the surface of the phosphorus-carbon material. Combined with an acid-resistant PAA binder, the pH value of the slurry is adjusted to form a stable phosphorus-carbon negative electrode aqueous slurry.

Benefits of technology

It significantly improves the stability of the slurry and the processing performance of the electrode, solves the problems of binder deactivation and electrode cracking caused by acidic environment in traditional methods, and enhances the electrochemical performance of lithium-ion batteries.

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Abstract

本发明公开了一种磷碳负极水系浆料及其制备方法,属于锂电池材料技术领域。该制备方法包括以下步骤:将磷碳材料与导电剂混合,得到前驱体;向所述前驱体中加入碱性锂盐,反应后得到混合料A;再向所述混合料A中加入耐酸性聚丙烯酸类粘结剂并拌匀,得到混合料B;向混合料B中加入纤维素类增稠剂并拌匀,得到混合料C;向混合料C中加入橡胶类粘结剂,得到所述磷碳负极水系浆料。本发明通过先加导电剂搅拌、后加碱性锂盐的特定工艺顺序,在磷碳材料表面原位生成磷酸锂快离子导体并调节浆料pH值,结合耐酸性PAA粘结剂的使用,显著提高了浆料稳定性、极片加工性能和电池电化学性能。
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