高硫烟气脱硝保硫的资源化方法及应用

By spontaneously generating solid (NOx)a-(SOx)b-(H2O)c in high-sulfur flue gas, the problem of NOx removal in high-sulfur flue gas is solved, achieving efficient denitrification, sulfur preservation, and resource utilization, while avoiding equipment corrosion and secondary pollution.

CN122032289BActive Publication Date: 2026-07-17UNIV OF SCI & TECH BEIJING

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
UNIV OF SCI & TECH BEIJING
Filing Date
2026-04-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies have difficulty selectively removing NOx from high-sulfur flue gas, leading to corrosion of the acid production system, decreased sulfuric acid purity, and difficulties in tail gas treatment, as well as secondary pollution problems.

Method used

In high-sulfur flue gas, under spontaneous reaction conditions, taking advantage of the fact that the SOx concentration is higher than NOx, NOx reacts with SOx and H2O to generate solid (NOx)a-(SOx)b-(H2O)c, thus achieving spontaneous denitrification and sulfur retention. The generated solids are then used for agricultural fertilizers and water purification.

Benefits of technology

It achieves efficient NOx removal, avoids equipment corrosion and sulfur resource loss, and the generated solids can be used as resources, solving the dual objectives of the acid production system and avoiding secondary pollution.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明属于高硫烟气治理技术领域,具体涉及一种高硫烟气脱硝保硫的资源化方法及应用。所述高硫烟气脱硝保硫的资源化方法包括如下步骤:高硫烟气经脱硝处理后制酸处理;所述脱硝处理包括如下步骤:高硫烟气在自发反应条件下进行自发反应脱硝;所述自发反应条件包括恒温微压;其中,恒温的温度为180℃~450℃;微压的压力为1.01 atm~1.5 atm。本发明实施例提供的高硫烟气脱硝保硫的资源化方法,全过程不引入氨、臭氧等外来氧化 / 还原剂,从源头上避免了硫酸氢铵堵塞、氨逃逸、臭氧泄漏等二次污染问题。
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