一种低氧超细锆粉及其制备方法

By constructing ammonium polyacrylate anchoring points and a calcium ion crosslinking layer on the surface of zirconium powder, combined with a polyethylene glycol outer network, the problem of particle adhesion and agglomeration during the deoxidation process of ultrafine zirconium powder was solved, achieving a synergistic improvement in low oxygen content and ultrafine particle size, thus enhancing the processing performance of the powder.

CN122033245BActive Publication Date: 2026-07-17ZHUZHOU RUNFENG NEW MATERIAL CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
ZHUZHOU RUNFENG NEW MATERIAL CO LTD
Filing Date
2026-04-01
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the existing technology, metallurgical adhesion and agglomeration easily occur between particles during the deoxidation process of ultrafine zirconium powder calcium hydride, resulting in increased particle size and wider particle size distribution, making it impossible to simultaneously achieve low oxygen content and ultrafine dispersibility.

Method used

Ammonium polyacrylate anchoring points are constructed on the surface of zirconium powder particles and combined with in-situ crosslinking of calcium ions to form a stable confinement layer. Subsequently, a long and short chain polyethylene glycol outer isolation network is constructed. Through the kinetic matching of calcium hydride deoxygenation reaction, particle adhesion and agglomeration are inhibited.

Benefits of technology

It achieves deep deoxidation of low-oxygen ultrafine zirconium powder, maintains ultrafine particle size and good dispersibility, improves the overall processing performance of powder, and exhibits excellent loose density, tap density and flowability, with good adaptability.

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Abstract

本发明涉及金属粉末技术领域,具体涉及一种低氧超细锆粉及其制备方法。该制备方法通过在锆粉表面顺序构建聚丙烯酸铵锚定位点、钙离子交联层以及长链与短链聚乙二醇复合包覆层,形成协同作用的多层界面调控体系,从而在高温脱氧过程中有效隔离颗粒、抑制粘连。所得锆粉氧含量显著降低,同时能良好保持超细粒径,并具有优异的松装密度、振实密度、流动性及压制成形性。
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