偶氮化合物光化学合成苯并[c]噌啉类化合物的方法

CN122036623BActive Publication Date: 2026-07-17SHANDONG JINKELI POWER SOURCES TECH +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHANDONG JINKELI POWER SOURCES TECH
Filing Date
2026-04-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing methods for synthesizing benzo[c] oxaloline compounds suffer from problems such as high toxicity of raw materials, poor selectivity, numerous byproducts, low yield, harsh reaction conditions, severe equipment corrosion, high catalyst costs, insufficient environmental friendliness, and difficulty in large-scale production, making it difficult to achieve industrial application.

Method used

Benzo[c]cenline compounds are synthesized by photochemical reaction of azobenzene compounds with Lewis acids and oxidants in organic solvents under white light irradiation. The reaction conditions are mild, the products are easy to separate, and there are few byproducts, making it suitable for large-scale industrial production.

Benefits of technology

It achieves efficient synthesis of low-toxicity raw materials, the products are easy to separate, suitable for industrial production, reduces production costs, simplifies operation procedures, and improves yield and selectivity.

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Abstract

本发明属于有机合成技术领域,具体涉及偶氮化合物光化学合成苯并[c]噌啉类化合物的方法。所述偶氮化合物光化学合成苯并[c]噌啉类化合物的方法,包括以下步骤:将偶氮苯类化合物、路易斯酸、氧化剂加入到有机溶剂中,在40‑50℃、白光照射条件下进行反应,完成反应后用水淬灭,然后经分离提纯,得到产物苯并[c]噌啉类化合物。本发明操作简单,反应物的毒性较低,无需添加贵金属,产物易分离且产率高。
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