基于电化学阻抗谱的锂电池SOH的故障监测方法

By obtaining reference parameters from the SOH monitoring of lithium batteries, removing parasitic impedance and filtering out noise, and extracting the constant phase angle frequency band slope of the electrochemical impedance spectrum, the problem of misjudgment caused by lithium plating phenomenon and positive electrode coupling in existing methods is solved, and high-precision monitoring of lithium battery faults is achieved.

CN122043293BActive Publication Date: 2026-07-17BEIJING ZHONGHAIJICHUANG SCI TECH DEV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
BEIJING ZHONGHAIJICHUANG SCI TECH DEV
Filing Date
2026-02-27
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing methods for monitoring the state of charge (SOH) of lithium batteries based on electrochemical impedance spectroscopy suffer from severe coupling between local lithium plating phenomena and the positive electrode's state of charge in in-situ non-destructive testing scenarios for full-cell batteries. This leads to the easy confusion of traditional impedance spectral parameters with other interfacial side reactions, making it difficult to accurately identify lithium plating faults on the negative electrode and reducing the reliability and accuracy of fault monitoring.

Method used

By obtaining the reference interface roughness parameters and area magnification factor under set state of charge, temperature and resting time, parasitic impedance is removed, noise is filtered out, the constant phase angle frequency band slope of the denoised interface impedance spectrum is extracted, the current interface roughness parameters are calculated and compared with the reference value, and the fault monitoring results are output.

Benefits of technology

Bypassing the attribution ambiguity caused by full-cell polarization coupling and internal resistance drift, it significantly improves the accuracy and reliability of early internal abnormal state monitoring of lithium batteries, avoids confusion of traditional judgment parameters, and can map the drastic changes in surface morphology caused by lithium plating on the negative electrode.

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Abstract

本发明涉及锂离子测试技术领域,公开了基于电化学阻抗谱的锂电池SOH的故障监测方法,包括:首先在设定的测试条件下获取无故障状态下的参考界面粗糙度参量与参考面积放大系数;接着对待测锂电池施加交流激励信号并采集原始阻抗数据;经高频寄生阻抗剥离与去噪重构后,获得去噪界面阻抗谱;通过计算阻抗相角随频率变化的导数值,锁定具备恒定相角响应的目标频段;在该频段内提取虚部数值的演化斜率,计算当前界面粗糙度参量并转换为当前面积放大系数;最后计算与参考系数的偏差值,并与判定阈值比对以输出监测结果。
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