一种磷酸锰铁锂正极材料及其制备方法

The lithium manganese iron phosphate cathode material was prepared by solution combustion synthesis and ultrasonic vacuum permeation technology, which solved the problems of uniform mixing of manganese and iron and construction of porous structure, improved the rate performance and cycle stability of the material, and realized a green and efficient preparation process.

CN122059448BActive Publication Date: 2026-07-17RENMIN UNIVERSITY OF CHINA

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
RENMIN UNIVERSITY OF CHINA
Filing Date
2026-04-23
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing methods for preparing lithium manganese iron phosphate are difficult to achieve atomic-level uniform mixing of manganese and iron, and it is also difficult to construct porous microstructures that are conducive to ion transport, resulting in insufficient rate performance and cycle stability of the material.

Method used

Manganese-iron composite oxide precursors were prepared by solution combustion synthesis. A three-dimensional porous sponge-like structure was formed through a self-propagating reaction. Lithium, phosphorus and carbon sources were introduced into the framework through ultrasonic vacuum-assisted infiltration and ultrafast freezing technology. Subsequently, lithium manganese-iron phosphate cathode material was formed by low-temperature sintering.

Benefits of technology

Atomic-level uniform mixing of manganese and iron elements was achieved, constructing a porous structure that facilitates ion transport, improving the rate performance and cycle stability of the material. At the same time, the process is simple, environmentally friendly, and suitable for industrial applications.

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Abstract

本发明涉及锂离子电池技术领域,具体涉及一种磷酸锰铁锂正极材料及其制备方法,将锰源、铁源和有机燃料溶解于溶剂中,混合均匀得到混合溶液,通过溶液燃烧合成法引发自蔓延反应,反应结束后获得具有三维多孔海绵状微观结构的锰铁复合氧化物前驱体。本发明的核心优势在于直接、原位地构建了三维多孔海绵状的前驱体骨架,而非依赖任何外加模板。这种自生型多孔结构赋予了前驱体巨大的比表面积和相互贯通的孔道网络。
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