掺硫多孔碳、磷碳复合材料及其应用

By using ion exchange resin or ionic liquid as a carbon source in porous carbon materials, combined with high-temperature pore formation and low-temperature treatment, a stable CS covalent bond structure is formed, which solves the problem of uneven sulfur doping and improves the electrochemical performance and cycle stability of phosphorus-carbon composite materials.

CN122068031BActive Publication Date: 2026-07-17HEFEI GUOXUAN KEHONG NEW ENERGY TECH CO LTD
View PDF 3 Cites 0 Cited by

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HEFEI GUOXUAN KEHONG NEW ENERGY TECH CO LTD
Filing Date
2026-04-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The uneven distribution of sulfur doping and weak chemical bonding in existing porous carbon materials affect the first-cycle coulombic efficiency, rate performance and cycle life of phosphorus-carbon composite materials.

Method used

Using ion exchange resin or ionic liquid as the carbon source, controllable microporous and mesoporous structures are formed through high-temperature pore formation, sulfidation, and low-temperature treatment. Abundant CS covalent bonds and stable thiophene-like structures are formed in the carbon framework, achieving uniform sulfur doping.

Benefits of technology

It improves the uniformity and chemical bonding strength of sulfur doping, enhances the deposition efficiency of phosphorus in porous carbon, and improves the kinetic properties and cycle stability of phosphorus-carbon composites.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure CN122068031B_ABST
    Figure CN122068031B_ABST
Patent Text Reader

Abstract

本发明公开了掺硫多孔碳、磷碳复合材料及其应用,属于碳材料制备技术领域。该制备方法包括步骤:提供碳源,所述碳源为离子交换树脂或离子液体中的一种或两种以上的混合;在CO2 / 非反应气体的混合气氛下对所述碳源进行高温造孔;然后通入含硫有机化合物的热解气,高温硫化,最后在150‑450℃下进行低温处理,形成C‑S共价键和稳定的噻吩类结构。通过该制备方法增加碳骨架和硫的化学结合,实现了硫在多孔碳中的均匀掺杂,有效解决了现有技术中硫掺杂分布不均匀、碳骨架和硫的结合不牢固的问题。并且,增强了磷的沉积效率,促进磷在多孔碳中的沉积均匀性,提高了磷碳的动力学性能,从而提高了二次电池的电化学性能。
Need to check novelty before this filing date? Find Prior Art