一种粉煤灰基低硅铝比双晶型分子筛的制备方法及应用

By controlling the silicon-to-aluminum ratio and alkali ratio in fly ash, low silicon-to-aluminum ratio NaA and NaX bicrystalline molecular sieves can be directly synthesized, solving the problem of needing to add additional silicon and aluminum sources in existing technologies, and achieving low-cost and efficient heavy metal removal.

CN122079187BActive Publication Date: 2026-07-17ZHEJIANG BAIMA LAKE LABORATORY CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
ZHEJIANG BAIMA LAKE LABORATORY CO LTD
Filing Date
2026-04-27
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies require the addition of silicon and aluminum sources in the process of preparing molecular sieves from fly ash, and it is difficult to synthesize dicrystalline molecular sieves, resulting in low product purity and crystallinity, and high cost.

Method used

Using fly ash as raw material, without adding silicon or aluminum sources, low-silicon-aluminum-ratio NaA and NaX bicrystalline molecular sieves are synthesized by controlling the silicon-aluminum ratio, sodium carbonate calcination activation, and alkali ratio, and by aging and low-temperature hydrothermal crystallization.

Benefits of technology

A low-cost synthesis of low-silicon-to-aluminum ratio bicrystalline molecular sieve was achieved, which improved the resource utilization rate of fly ash and showed a high efficiency in removing heavy metals from low-concentration wastewater.

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Abstract

本发明涉及分子筛的技术领域,公开了一种粉煤灰基低硅铝比双晶型分子筛的制备方法及应用,所述方法包括如下步骤:(1)将硅铝比为2.5~3.5的粉煤灰与碳酸钠混合,煅烧后研磨,得到粉末;(2)将粉末加入氢氧化钠溶液中,溶液中氧化钠与氧化硅的物质的量之比为2.5:1~1.125,进行陈化,得到混合液;(3)将混合液进行晶化,再经过滤、干燥后,得到含A型和X型的低硅铝比双晶型分子筛。本发明采用粉煤灰作为原料,不外加硅源和铝源,直接进行陈化和水热晶化,合成低硅铝比NaA和NaX双晶型分子筛,合成方法简单易于放大,成本较低,并且能够用于废水中低浓度重金属的高效脱除。
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Citation Information

Patent Citations

  • Method for preparing fly ash-based molecular sieve

    CN115432713A

  • Method for preparing low-silicon Na-A / X cocrystallization zeolite in pure sodium aluminosilicate system

    CN102557067A

  • Preparation method of NaA molecular sieve by taking fly ash as raw material

    CN107697927A