一种碾压混凝土用聚羧酸复合型减水剂及其制备方法

The polycarboxylate composite water-reducing agent prepared by copolymerization adopts a "core-shell" structure formed by modified hydrophobic unsaturated monomers, polyether macromonomers, and unsaturated carboxylic acids. This solves the problems of mismatch in construction performance and poor stability of polycarboxylate water-reducing agents in roller-compacted concrete, and achieves a synergistic effect of high water reduction, low viscosity, long slump retention, and enhanced crack resistance. It is adaptable to the differences in raw materials in various regions and extreme construction environments.

CN122080329BActive Publication Date: 2026-07-17BEIJING HOUDE TRANSPORTATION TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
BEIJING HOUDE TRANSPORTATION TECH CO LTD
Filing Date
2026-04-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing polycarboxylate superplasticizers in roller-compacted concrete suffer from problems such as poor raw material adaptability, mismatched construction performance, insufficient environmental tolerance, and poor stability. They are difficult to achieve the synergistic effects of high water reduction, low shrinkage, crack resistance, and interlayer reinforcement at the same time. Furthermore, the preparation process suffers from problems such as low monomer conversion rate and uneven molecular weight distribution, which cannot meet the needs of green building and multi-scenario construction.

Method used

A polycarboxylate composite water-reducing agent for roller-compacted concrete was prepared by copolymerization reaction. Modified hydrophobic unsaturated monomer C was used with polyether macromonomer and unsaturated carboxylic acid to form a multi-level macromolecule with a "core-shell" structure. Combined with emulsifier and solubilizer system, a dynamic hydrophobic association network was constructed to improve early strength and water retention, reduce construction sensitivity, and enhance freeze-thaw resistance and durability.

Benefits of technology

It achieves a synergistic effect of high water reduction rate, low viscosity, long slump retention and enhanced crack resistance, solves the construction adaptability and durability problems of roller-compacted concrete, meets the standards for large-scale production and certification, and reduces construction difficulty and cost.

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Abstract

本发明涉及碾压混凝土用外加剂技术领域,尤其是涉及一种碾压混凝土用聚羧酸复合型减水剂及其制备方法,由包括以下质量份数的原料经共聚反应制得:聚醚大单体30‑50份、改性疏水型不饱和单体C 1‑20份和不饱和羧酸1‑30份;其中,所述改性疏水型不饱和单体C的制备原料包括不饱和疏水性羧酸酯类单体、乳化剂、增溶剂和水,且所述不饱和疏水性羧酸酯类单体、所述乳化剂、所述增溶剂和所述水的质量比为(3.0‑5.5):(0.5‑1.0):(0.5‑1.5):(2.5‑3.5)。本发明通过上述层层递进、协同增效的作用机制,在确保碾压混凝土高减水率的前提下,系统性地解决了保水性、施工适应性与长期耐久性等多重技术难题,实现了综合性能的全面优化。
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