固体氧化物燃料电池积炭约束双输入模型预测控制方法

By constructing an 11-state-variable DIR-SOFC model and a dual-input model predictive control method, the constraints of carbon deposition, fuel utilization, and thermal safety in DIR-SOFC are solved by coordinating methane flow rate and steam flow rate, thus achieving efficient catalyst activity protection and system stability.

CN122091650BActive Publication Date: 2026-07-17JILIN UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
JILIN UNIVERSITY
Filing Date
2026-04-27
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing model predictive control methods cannot effectively coordinate the three constraints of carbon deposition, fuel utilization and thermal safety in direct internal reforming solid oxide fuel cells (DIR-SOFC), leading to irreversible degradation of catalyst activity. Furthermore, existing methods fail to suppress carbon deposition by actively adjusting the S/C ratio through steam flow.

Method used

An 11-state variable DIR-SOFC controlled object model was constructed. A dual-input model predictive control method was adopted. Through coordinated control of methane flow and steam flow, combined with a hierarchical constraint system of carbon deposition rate, fuel utilization rate and thermal gradient, optimization control was performed using a nonlinear predictive trajectory linearization framework.

Benefits of technology

It effectively suppressed the carbon deposition rate, improved fuel utilization and thermal safety, controlled catalyst activity loss within 1.4%, and the average single-step calculation time was 133ms, meeting real-time constraints. The number of carbon safety violations was reduced from 11 to 0, improving the long-term reliability of the system.

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Abstract

本发明属于固体氧化物燃料电池控制与优化技术领域,尤其为固体氧化物燃料电池积炭约束双输入模型预测控制方法。包括以下步骤:S1:构建含11个状态变量的DIR‑SOFC被控对象模型;S2:通过序列二次规划求解最优控制增量;S3:构建约束体系;S4:引入随负荷电流密度线性调整的输出电压自适应设定值。本发明模型维度由现有技术的3状态扩展至11状态,完整涵盖六路气相分压、碳积累‑催化剂活性双线性耦合及三区热动态,ODE白箱预测引擎精确反映MSR非线性和积炭正反馈,相比ARMAX黑箱预测误差从约3%降至0.8%以内,平均单步计算耗时133ms,满足采样时间1s的实时约束。
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