一种无机有机复合固态电解质膜及其制备方法

By modifying PEO and using mixed solvents and additives to prepare inorganic-organic composite solid electrolyte membranes, the problem of uneven dispersion of PEO in polar solvents was solved, and the ionic conductivity and lithium-ion transport rate of sulfide solid electrolytes were improved.

CN122091702BActive Publication Date: 2026-07-17GUIZHOU MATERIAL IND TECH INSTITUE

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
GUIZHOU MATERIAL IND TECH INSTITUE
Filing Date
2026-01-04
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the wet preparation of sulfide solid electrolyte membranes, PEO is easily soluble in polar solvents, leading to structural decomposition and performance degradation. Furthermore, PEO is unevenly dispersed in anisole solvent, affecting the encapsulation and dispersion effect of the sulfide solid electrolyte.

Method used

Methyl-terminated polyethylene oxide was used to modify PEO, and Li3PO4 was added to a mixed solvent of anisole and tetrahydrofuran to promote the dispersion of PEO in the mixed solvent, forming a homogeneous slurry, and thus preparing an inorganic-organic composite solid electrolyte membrane.

Benefits of technology

It improves the ionic conductivity of sulfide solid electrolytes, inhibits PEO degradation, increases lithium-ion transport rate, and enhances the performance of composite solid electrolyte membranes.

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Abstract

本发明提供一种无机有机复合固态电解质膜及其制备方法,属于固态电解质膜技术领域。本发明以苯甲醚和四氢呋喃为混合溶剂溶解甲基封端的PEO,四氢呋喃可以减弱PEO链上的醚氧原子与苯甲醚的相互作用,促进PEO在混合溶剂中的分散,促进形成均质涂覆浆料;而甲基封端聚环氧乙烷不仅可以改善硫化物固态电解质与不导离子的粘结剂复合成膜后离子电导率的损失,其甲基封端还可以抑制聚环氧乙烷对硫化物固态电解质的降解作用,更好保留硫化物的高性能特质;另外,通过添加Li3PO4提高聚环氧乙烷中的锂离子的传输速率,从而提升复合固态电解质膜的离子电导率。
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