一种基于增材制造的贵金属催化剂及其制备方法

By employing polymerization-induced phase separation and amphiphilic ligand molecule assembly, the problem of coating peeling off in additive manufacturing catalysts was solved, achieving stable distribution of precious metals on the catalyst surface and high-efficiency catalytic performance, which is suitable for industrial waste gas treatment.

CN122098549BActive Publication Date: 2026-07-17SHAANXI ROCK NEW MATERIALS CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHAANXI ROCK NEW MATERIALS CO LTD
Filing Date
2026-04-28
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing additive manufacturing catalysts are prone to coating peeling and loss under fluid shear, resulting in decreased catalytic activity and failing to meet the requirements of high-speed industrial operation.

Method used

A polymerization-induced phase separation and amphiphilic ligand molecular assembly method is adopted. By complexing noble metal precursors with oleylamine, the noble metal components are migrated to the pore surface through chemical coupling and phase separation mechanical action. Multi-level pore solidification is achieved through multi-stage heat treatment to ensure the stable distribution of noble metals on the catalyst surface.

Benefits of technology

It improves the resistance of precious metal catalysts to fluid shearing and high-temperature sintering, extends the theoretical service life of the catalyst, maintains high active exposure surface and mass transfer efficiency, and is suitable for industrial waste gas treatment.

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Abstract

本申请涉及催化剂技术领域,更具体地说,它涉及一种基于增材制造的贵金属催化剂及其制备方法。本申请的基于增材制造的贵金属催化剂的制备方法,包括如下步骤:1)将氯铂酸六水合物、油胺、有机溶剂混合均匀,在40‑50℃下搅拌1‑3h,然后除去有机溶剂,得到复合物;2)将步骤1)制得的复合物与1,6‑己二醇二丙烯酸酯、三羟甲基丙烷三丙烯酸酯、光引发剂、致孔剂混合均匀,然后加入氧化铝粉体、分散剂,球磨,脱泡,制得浆料;3)将步骤2)制得的浆料进行3D打印,清洗,得到生坯;4)将步骤3)得到的生坯先在280‑330℃保温3‑5h,然后在350‑450℃下保温1‑2h,然后在含氢气氛下于850‑950℃下保温2‑4h,冷却,即得。本申请制得的催化剂能够大大降低贵金属的剥落脱失。
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