多金属氧酸盐复合N掺杂碳量子点及其制备方法和应用

By preparing N-doped carbon quantum dots via a hydrothermal method and combining it with a stirring and settling process, a tight bond between polyoxometalates and N-doped carbon quantum dots was achieved, solving the problems of weak bonding and easy aggregation. This improved catalytic performance and stability, making it suitable for large-scale application in photocatalytic carbon dioxide reduction.

CN122098660BActive Publication Date: 2026-07-17INNER MONGOLIA UNIVERSITY +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
INNER MONGOLIA UNIVERSITY
Filing Date
2026-04-30
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing composite methods of polyoxometalates and N-doped carbon quantum dots suffer from problems such as weak bonding, loose interfacial contact, and easy agglomeration, resulting in poor composite material stability, rapid decay of catalytic performance, and complicated and costly preparation methods, making it difficult to apply on a large scale.

Method used

N-doped carbon quantum dots were synthesized in one step using a hydrothermal method. Combined with a stirring and static synergistic assembly process, the close bonding between polyoxometalates and N-doped carbon quantum dots was achieved by controlling the ratio of reactants. During the preparation process, the pH of the system was controlled to 7 to form matching charge characteristics, promote electrostatic interaction and coordination bonding, and construct a stable interfacial bonding structure.

Benefits of technology

The process achieves tight bonding of polyoxometalate composite N-doped carbon quantum dots, which enhances light absorption capacity and electron separation efficiency. It exhibits excellent catalytic activity and stability, is simple and environmentally friendly, suitable for large-scale production, and demonstrates excellent catalytic performance in photocatalytic carbon dioxide reduction reaction.

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Abstract

本发明公开了一种多金属氧酸盐复合N掺杂碳量子点及其制备方法和应用,属于光催化纳米复合材料制备方法技术领域。多金属氧酸盐复合N掺杂碳量子点的制备方法为:将钼酸盐和水混合,得到钼酸盐水溶液;将过渡金属盐、过氧化氢溶液和水混合,得到混合溶液;将钼酸盐水溶液加热至沸腾,然后加入混合溶液,过滤得到多金属氧酸盐前驱体热溶液;将多金属氧酸盐前驱体热溶液和N掺杂碳量子点水溶液混合搅拌,冷却至室温,静置,将沉淀洗涤干燥得到多金属氧酸盐复合N掺杂碳量子点。本发明制备的多金属氧酸盐复合N掺杂碳量子点在光催化二氧化碳还原反应中,合成气CO和H2产率比为1.3:1,产率>40000μmol·g‑1·h‑1。
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