一种C / SiC-ZrB2-HfB2-Cu复合材料及其制备方法

C/SiC-ZrB2-HfB2-Cu composite materials were prepared by vacuum centrifugal impregnation and ceramic metallization processes, which solved the service problems of existing ceramic matrix composite materials in the extreme environment of scramjet engines. This resulted in a low-cost, short-cycle, and high-performance thermal protection material with excellent ablation resistance and thermal conductivity.

CN122102699BActive Publication Date: 2026-07-17INST OF METAL RESEARCH - CHINESE ACAD OF SCI

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
INST OF METAL RESEARCH - CHINESE ACAD OF SCI
Filing Date
2026-04-28
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing ceramic matrix composite materials are difficult to meet the service requirements of over 2500°C in the extreme environment of scramjet engines. They are costly and have long preparation cycles, making it difficult to achieve low-cost, short-cycle, and high-performance thermal protection materials.

Method used

A C/SiC-ZrB2-HfB2-Cu composite material was prepared by vacuum centrifugal impregnation and ceramic metallization process. By forming a three-dimensional continuous network structure of Cu conductive agent and uniform dispersion of ZrB2-HfB2 particles in the matrix, high thermal conductivity and ablation resistance were achieved.

Benefits of technology

The material exhibits excellent ablation resistance and low surface temperature characteristics at temperatures above 2500℃, significantly reducing surface temperature, improving mechanical properties and reducing linear ablation rate, while also lowering cost and shortening preparation cycle.

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Abstract

本发明涉及陶瓷基复合材料制备技术领域,具体涉及一种C / SiC‑ZrB2‑HfB2‑Cu复合材料及其制备方法。包括如下步骤:(1)配置C‑ZrB2‑HfB2混合料浆;(2)将带有热解炭界面层的碳纤维预制体置于混合料浆中,真空离心浸渍处理,取出后干燥,制得毛坯;(3)将毛坯置于坩埚中,用硅铜合金包埋,制得C / SiC‑ZrB2‑HfB2‑Cu复合材料。本发明利用真空和离心力的双重驱动作用,确保了料浆在毛坯中充分、均匀渗透。较传统C / SiC‑Cu或C / SiC‑ZrC‑Cu复合材料,陶瓷组元在材料内部分布更均匀,材料耐温能力更强,且线烧蚀率更低;材料力学性能更强,弯曲强度可达250MPa以上。
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