A persulfate slow-release system based on non-radical oxidation and a construction method and application thereof

By constructing a core-shell structured non-radical persulfate oxidation slow-release system and utilizing a Mg-Fevac-LDH/biochar composite catalyst, the problems of easy aggregation of the layered structure and metal ion leaching in the persulfate catalytic system in soil remediation were solved, achieving efficient, stable and targeted removal of PAHs.

CN122104236APending Publication Date: 2026-05-29SHANDONG UNIV OF SCI & TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
SHANDONG UNIV OF SCI & TECH
Filing Date
2026-01-29
Publication Date
2026-05-29

AI Technical Summary

Technical Problem

Existing persulfate catalytic systems for soil remediation suffer from problems such as easy aggregation of layered structures, easy leaching of metal ions, insufficient distribution of oxidants in the remediation area, low remediation efficiency, and back diffusion of pollutants, making it difficult to effectively degrade organic pollutants such as polycyclic aromatic hydrocarbons (PAHs).

Method used

A non-radical oxidation-based persulfate slow-release system was adopted. By constructing a core-shell structure, using Mg-Fevac-LDH/biochar composite material as a catalyst, persulfate as an oxidant, polycaprolactone as a core structure binder, bentonite as a shell structure binder, and quartz sand as a pore structure modifier, a non-radical oxidation system dominated by high-valence iron-oxygen was formed to achieve targeted removal of PAHs.

Benefits of technology

It achieves efficient, stable, targeted and long-term removal of PAHs pollutants, with a catalytic degradation efficiency of up to 83.2%, solving the problems of low remediation efficiency and secondary pollution risk in existing technologies.

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Abstract

The application discloses a persulfate slow-release system based on non-radical oxidation and a construction method and application thereof, and belongs to the technical field of soil organic pollutant treatment. The persulfate slow-release system is composed of a core structure and a shell structure coated outside the core structure, raw material components of the core structure include polycaprolactone, persulfate and quartz sand, and raw material components of the shell structure include Mg-Fe vac -LDH / biochar composite material, bentonite and quartz sand; Mg-Fe vac -LDH / biochar composite material contains cation Fe vacancies. The application utilizes the double regulation advantages of biochar and cation Fe vacancies, realizes construction of a non-radical oxidation system dominated by high-valence iron-oxygen species, and simultaneously introduces a control slow-release technology to prepare a persulfate slow-release agent with a "core-shell" structure, and the catalytic degradation efficiency of the persulfate slow-release agent on benzopyrene in soil is as high as 83.2%.
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