一种高强热缩膜及其制备工艺

By constructing a synergistic mechanism between the surface quaternary graft copolymer and the core LDPE/EVA/POE ternary system, combined with a chemical bonding network, the comprehensive performance issues of heat shrink film in terms of transparency, strength, shrinkage rate and low-temperature toughness were solved, resulting in a high-strength, high-shrinkage and environmentally friendly non-toxic heat shrink film.

CN122125985BActive Publication Date: 2026-07-17SICHUAN YIHAN NEW MATERIAL TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SICHUAN YIHAN NEW MATERIAL TECH CO LTD
Filing Date
2026-05-07
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing heat shrink films cannot simultaneously achieve a combination of high transparency, high strength, high shrinkage rate, ultra-low temperature toughness, and environmentally friendly and non-toxic properties.

Method used

By constructing the molecular structure of the surface quaternary graft copolymer (PMP-g-EMH), the synergistic mechanism of the core LDPE/EVA/POE ternary system and the reactive compatibilizer POE-g-GMA, and through the maleic anhydride-epoxy ring-opening reaction chemical bonding network between the surface and core layers, interlayer chemical bonding is achieved.

Benefits of technology

It achieves high transparency (haze ≤3%, light transmittance ≥94%), high strength (tensile strength ≥55MPa), high shrinkage (transverse shrinkage ≥55% at 100℃) and ultra-low temperature toughness (good flexibility at -50℃). The material is also environmentally friendly and non-toxic, making it suitable for food packaging and low-temperature environments.

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Abstract

本发明公开了一种高强热缩膜及其制备工艺,涉及包装材料技术领域。高强热缩膜为多层共挤双向拉伸膜,包括表层和芯层,表层包括以下原料:mLLDPE、PMP、四元接枝共聚物、纳米二氧化硅、抗氧剂、芥酸酰胺;芯层包括以下原料:LDPE、EVA、聚烯烃弹性体、POE‑g‑GMA、抗氧剂。四元接枝共聚物以EMH为主链、以PMP为接枝侧链。高强热缩膜的制备工艺,包括以下步骤:制备表层粒料和芯层粒料;将表层粒料和芯层粒料经共挤出模头挤出形成多层膜坯;将多层膜坯进行冷却、定型后,先纵向拉伸,再横向拉伸;将拉伸后的薄膜进行热定型处理,冷却至室温,即得高强热缩膜。本发明的热缩膜能够同时兼顾高透明度、高强度、高收缩率、超低温韧性与环保无毒的综合性能。
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