基于变温萃取溶液离子热效应的制冷热泵系统

By utilizing the subcooling properties of sodium acetate trihydrate and the LCST properties of ionic liquids through a solid-liquid phase change thermodynamic cycle and an ionic liquid regeneration cycle, the high energy consumption and clogging problems of electrodialysis regeneration of high-concentration salt solutions are solved, achieving efficient cooling and heating while meeting environmental protection requirements.

CN122129802BActive Publication Date: 2026-07-17SOUTHEAST UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SOUTHEAST UNIV
Filing Date
2026-04-30
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing ionothermal refrigeration systems, high energy consumption and crystallization blockage occur during the electrodialysis regeneration of high-concentration salt solutions, resulting in low refrigeration and heating efficiency.

Method used

A solid-liquid phase change thermodynamic circulation loop and an ionic liquid regeneration circulation loop are adopted. Taking advantage of the supercooling characteristics of sodium acetate trihydrate and the minimum critical co-solution temperature of ionic liquid, high-concentration solution regeneration is achieved through extraction separation and triggered crystallization. Combined with a low-grade heat source to drive the regeneration process, crystallization blockage is avoided.

Benefits of technology

It enables the regeneration of solutions with higher concentrations, improves cooling and heating performance, reduces system energy consumption, reduces equipment size, adapts to various cooling and heating scenarios, and meets environmental protection requirements.

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Abstract

本发明公开了一种基于变温萃取溶液离子热效应的制冷热泵系统,包括:固液相变热力循环回路,该回路包括依次连接分别用于工质稀释、浓缩和结晶的溶解吸热单元、萃取分离单元和触发结晶单元;该回路中的工质在萃取分离单元中浓缩后能够以亚稳态过饱和溶液形式输送至触发结晶单元;离子液体再生循环回路,该回路与固液相变热力循环回路在萃取分离单元处耦合,该回路包括依次连接分别用于实现离子液体吸水和排水和散热的萃取分离单元和再生分离单元;再生分离单元内设有加热装置;再生分离单元向溶解吸热单元提供水,触发结晶单元向溶解吸热单元提供结晶产物;本发明能实现更高浓度溶液再生提高制冷与制热效果且更加节能。
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