一种浸没式ArF光刻胶组合物

By optimizing the combination of resin component I and resin component II, a spontaneous hydrophobic layer is formed, which solves the problems of process complexity and light transmittance of immersion ArF photoresist, and achieves efficient and clear photolithographic pattern formation and low defect rate.

CN122131545BActive Publication Date: 2026-07-17SUZHOU RAINBOW MATERIALS CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SUZHOU RAINBOW MATERIALS CO LTD
Filing Date
2026-04-30
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing immersion ArF photoresists suffer from complex processes, high difficulty in supporting processes, poor matching degree between photoresist and topcoat, and insufficient light transmittance. Furthermore, the fluorinated resin and the main resin are on the same molecular chain, which leads to incomplete cleaning after development and affects the roughness of the line edges.

Method used

A combination of resin component I and resin component II is used. Resin component I is a copolymer formed from methacrylate monomers, and resin component II is a fluorinated methacrylate homopolymer. By optimizing the molecular weight and ratio, a spontaneous hydrophobic layer is formed. Combined with photoacid generators and organic solvents, the process flow is simplified.

Benefits of technology

It achieves self-layering during baking, forming a dense hydrophobic layer to prevent water from damaging the underlying photoresist, reduce photoacid leaching, improve production efficiency, ensure smooth edges of photolithographic patterns and low defect rate, and simplify the production process.

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Abstract

本发明公开了一种浸没式ArF光刻胶组合物,所述光刻胶组合物包括ArF光刻胶树脂、光致产酸剂和有机溶剂,所述ArF光刻胶树脂由树脂组分Ⅰ、树脂组分Ⅱ组成,树脂组分Ⅰ与树脂组分Ⅱ的投加质量比为(2‑10):1。树脂组分Ⅰ为含酸不稳定基团的甲基丙烯酸酯主体树脂,树脂组分Ⅱ为含氟甲基丙烯酸酯均聚物。预烘烤时,低表面能的树脂组分Ⅱ向空气‑涂层界面迁移,形成疏水阻挡层,抑制组分溶出并维持≥85°的水接触角;高表面能的树脂组分Ⅰ向衬底界面排布,保证粘附性和光刻性能。本发明无需额外涂覆顶部抗反射涂层,简化工艺,提升分辨率及线条边缘粗糙度,适用于90nm以下半导体制造。
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