一种MOF衍生的CoS / FeS异质结构钠离子电池负极材料及其制备方法

By constructing a CoS/FeS heterostructure sodium-ion battery anode material, the problems of slow Na+ diffusion and structural collapse in sodium-ion batteries were solved by utilizing the synergistic effect of lattice distortion and interface, thus achieving an electrode material with high conductivity and long lifespan.

CN122144796BActive Publication Date: 2026-07-17INNER MONGOLIA UNIV OF SCI & TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
INNER MONGOLIA UNIV OF SCI & TECH
Filing Date
2026-04-30
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The slow diffusion of Na+ and the problem of crystal structure collapse in sodium-ion batteries make it difficult to select and design electrode materials. Traditional materials have kinetic lag, short cycle life, and are prone to structural collapse.

Method used

A CoS/FeS heterostructure sodium-ion battery anode material was constructed. Phytic acid was introduced as a phosphorus and carbon source and melamine as a nitrogen source through lattice distortion and interface synergistic effect to form a nitrogen and phosphorus doped amorphous carbon layer, construct a continuous conductive network, suppress electrolyte side reactions, and optimize electrode surface wettability.

Benefits of technology

It significantly shortens the Na+ transport path, improves the material's conductivity, extends cycle life, maintains high capacity and stability, and solves the common problems of electrolyte decomposition and capacity decay in sodium-ion batteries.

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Abstract

本发明涉及钠离子电池负极材料技术领域,具体涉及一种MOF衍生的CoS / FeS异质结构钠离子电池负极材料及其制备方法,包括以下步骤:将装有改性硫代乙酰胺的瓷舟置于管式炉的上游,装有改性Co / Fe‑MOF前驱体的瓷舟置于管式炉的下游,将管式炉内的温度升温至500‑520℃,并在惰性气体环境中保持2‑2.5h,得到MOF衍生的CoS / FeS异质结构钠离子电池负极材料。本发明通过构建CoS / FeS异质结构通过晶格畸变与界面协同效应,显著缩短Na+传输路径,降低嵌入 / 脱出能垒,完美匹配钠离子电池对大离子半径的适配需求,解决传统材料动力学滞后的核心瓶颈,改性步骤引入的碳层与植酸衍生官能团,显著增强电极表面润湿性,优化电解液浸润效率。
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