Wastewater treatment device and process of membrane separation and simultaneous biodegradation cycle

By using a flow-guiding baffle to separate the reactor and in-situ coupled membrane separation in the treatment of silicone oil production wastewater, the problems of long wastewater transfer time and membrane fouling are solved, achieving efficient wastewater treatment and membrane module maintenance, and extending the service life of the membrane module.

CN122144965APending Publication Date: 2026-06-05SHANGHAI JINGRI NEW MATERIAL TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
SHANGHAI JINGRI NEW MATERIAL TECH CO LTD
Filing Date
2026-04-03
Publication Date
2026-06-05

AI Technical Summary

Technical Problem

In the process of treating wastewater from silicone oil production, it takes a long time to transfer the wastewater from the bioreactor to the membrane separation zone, resulting in low treatment efficiency and the risk of membrane fouling.

Method used

Multiple flow guide baffles are used to divide the integrated reactor into an aerobic degradation zone, an anoxic denitrification zone, and an anaerobic hydrolysis zone. The membrane module support is directly connected to the aerobic degradation zone to achieve in-situ coupling of biodegradation and membrane separation. Combined with agitator, aeration components, and backwashing system, the wastewater treatment process is optimized.

Benefits of technology

It effectively shortens the wastewater treatment process, improves treatment efficiency, reduces the risk of membrane fouling, extends the service life of the membrane module, and enables the recycling of sludge and mixed liquor, thereby improving biodegradation efficiency and oil-water separation effect.

✦ Generated by Eureka AI based on patent content.

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Abstract

The application provides a wastewater treatment device and process of membrane separation and synchronous biodegradation cycle, and relates to the field of wastewater treatment.The device comprises a positioning mounting frame, a comprehensive reactor, a flow guide partition, a membrane assembly support, a limiting mounting box and a microporous aeration element.The comprehensive reactor is arranged on the front side of the positioning mounting frame.The flow guide partition is fixedly connected to the inner side of the comprehensive reactor, and multiple flow guide partitions divide the comprehensive reactor into an aerobic degradation zone, an anoxic denitrification zone and an anaerobic hydrolysis zone.The membrane assembly support is bolted to the inner side of the comprehensive reactor.The limiting mounting box is fixedly connected to the lower part of the comprehensive reactor.The microporous aeration element is fixedly connected to the inner side of the limiting mounting box.The application realizes in-situ coupling of biodegradation and membrane separation, saves a large amount of time and improves the treatment efficiency of wastewater.The application solves the problem that a long time is consumed in the wastewater transfer process, which affects the treatment efficiency of wastewater.
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Description

Technical Field

[0001] This invention relates to the field of wastewater treatment technology, and in particular to a wastewater treatment device and process for simultaneous membrane separation and biodegradation cycle. Background Technology

[0002] When treating wastewater generated during silicone oil production, the pH value needs to be adjusted in a wastewater equalization tank. After adjustment, the wastewater enters the demulsification and oil removal unit. The oil-removed wastewater enters the bioreactor, where the microorganisms in the wastewater are degraded. The degraded wastewater then enters the membrane separation zone, where PVDF hollow fiber ultrafiltration membranes intercept sludge, macromolecular organic matter, siloxanes, suspended solids, and other contaminants in the wastewater.

[0003] For example, CN109111013B discloses a method for treating wastewater containing water-soluble silicone oil generated during organosilicon production: after sedimentation in an oil separator for 48 hours, the floating scum at the top and the sedimented silica powder at the bottom are separated using a horizontal screw press; the wastewater containing water-soluble silicone oil is adjusted to pH 3-4 and then centrifuged to remove the precipitated silicone oil; the separated wastewater is subjected to air flotation for impurity removal and deep oxidation to oxidize the silicone oil dissolved in the wastewater into silica gel, and then a plate and frame filter press is used to remove the silica gel. The resulting saline wastewater is dehydrated by a triple-effect evaporator and used as a raw material for ion-exchange membrane caustic soda. This invention uses advanced equipment such as a horizontal screw press and a triple-effect evaporator to directly oxidize the water-soluble silicone oil in the wastewater into silica gel, with a conversion rate of over 99%. The biochemical properties of the treated wastewater are not less than 0.29, facilitating biochemical treatment. The wastewater treated by this invention meets national discharge standards, and the generated silica gel and crude salt can be used as downstream raw materials for organosilicon and caustic soda, demonstrating high practical value.

[0004] However, during the treatment process, wastewater first enters the bioreactor. After the pollutants are degraded, it needs to be transferred to the membrane separation zone through pipelines for solid-liquid and oil-water separation. The wastewater transfer process takes a long time, which affects the wastewater treatment efficiency. At the same time, sludge settling and silicone oil re-emulsification are likely to occur during the wastewater transfer process, resulting in a high risk of membrane fouling. Summary of the Invention

[0005] In view of this, the present invention provides a wastewater treatment device and process for simultaneous membrane separation and biodegradation cycle. It utilizes multiple baffles to divide the wastewater into an aerobic degradation zone, an anoxic denitrification zone, and an anaerobic hydrolysis zone. Simultaneously, the membrane module support is directly bolted to the aerobic degradation zone and the membrane module is suspended, achieving in-situ coupling of biodegradation and membrane separation. This avoids the need to transfer wastewater through pipelines between the bioreactor and membrane separation zone, effectively shortening the overall wastewater treatment process, saving significant time, and improving treatment efficiency. It also avoids sludge settling and silicone oil re-emulsification during wastewater transfer, reducing the risk of membrane fouling and extending the membrane module's lifespan. The reciprocating self-locking drive on the water quality equalization tank rotates the agitator, ensuring more uniform pH adjustment and stable operation of subsequent treatment processes. The demulsification reaction tank, combined with a settling inclined plate, enables preliminary sludge settling. The coordinated setup of the heated demulsification tank, centrifuge, and silicone oil storage tank not only efficiently separates silicone oil from the wastewater for resource recovery but also... The residual liquid after centrifugation is returned to the water quality equalization tank for reprocessing, achieving wastewater reuse and reducing resource waste. The coordinated use of the chemical washing tank, backwash pump, and water collection pipe enables timely and effective backwashing maintenance of the membrane module, ensuring the continuity of membrane separation performance. The mixed liquor return pump and sludge return pump transport the mixed liquor and sludge to the anoxic denitrification zone and anaerobic hydrolysis zone of the integrated reactor, respectively, achieving the recycling of sludge and mixed liquor, maintaining the stability of the microbial community within the reactor, and improving biodegradation efficiency. (Fan installation...) The linkage between the tank, airflow collection box, and microporous aeration components provides uniform and sufficient aeration to the integrated reactor, ensuring the degradation effect in the aerobic degradation zone. At the same time, the airflow generated by aeration can also purge the membrane module, reducing the adsorption of pollutants on the membrane surface and further reducing the probability of membrane fouling. The cooperation of the linear module, oil skimmer, and oil scraper can efficiently collect the floating oil in the demulsification reaction tank and guide it into the oil collection tank, and then transport it to the heated demulsification tank for subsequent treatment, improving the efficiency of oil-water separation and preventing floating oil from entering the subsequent treatment process and affecting the treatment effect.

[0006] This invention provides a wastewater treatment device and process for simultaneous membrane separation and biodegradation cycle, specifically comprising: a positioning mounting frame, a comprehensive reactor, flow guide baffles, a treatment structure, a reflux structure, a membrane module support, a limiting mounting box, and microporous aerators; the comprehensive reactor is located on the front side of the positioning mounting frame; multiple flow guide baffles are provided, evenly distributed and fixedly connected to the inner side of the comprehensive reactor, dividing the comprehensive reactor into an aerobic degradation zone, an anoxic denitrification zone, and an anaerobic hydrolysis zone; the treatment structure is located on the left side of the comprehensive reactor; the membrane module support is bolted to the aerobic degradation zone inside the comprehensive reactor, and multiple membrane modules are evenly suspended on the upper part of the membrane module support; the limiting mounting box is fixedly connected to the lower part of the comprehensive reactor; the microporous aerators are fixedly connected to the inner side of the limiting mounting box; and the reflux structure is located on the upper part of the positioning mounting frame.

[0007] Furthermore, the processing structure includes a chemical washing tank, a backwash pump, and a product water pump; the chemical washing tank is fixedly connected to the upper part of the positioning mounting frame; the backwash pump is bolted to the upper part of the chemical washing tank, and the input end of the backwash pump is connected to the chemical washing tank; the product water pump is bolted to the upper part of the chemical washing tank.

[0008] Furthermore, the treatment structure also includes a water quality conditioning tank, a water collection pipe, and a demulsification reaction tank; the water quality conditioning tank is connected to the integrated reactor via a pipe; the water collection pipe is fixedly connected to the lower part of the integrated reactor, and the input end of the product water pump is fixedly connected to the water collection pipe; a booster pump is installed at the upper part of the water quality conditioning tank, the input end of the booster pump is connected to the water quality conditioning tank, the output end of the booster pump is connected to the demulsification reaction tank via a pipe, and a settling inclined plate is installed at the upper part of the demulsification reaction tank.

[0009] Furthermore, the processing structure also includes a reciprocating self-locking drive and a stirring paddle; the reciprocating self-locking drive is bolted to the upper part of the water quality conditioning tank; the stirring paddle is rotatably connected to the middle part of the water quality conditioning tank, and the stirring paddle is coaxially fixedly connected to the output end of the reciprocating self-locking drive.

[0010] Furthermore, the processing structure also includes a heated demulsifying tank, a centrifuge, and a silicone oil storage tank; the heated demulsifying tank is connected to the demulsifying reaction tank via a pipeline; the centrifuge is connected to the heated demulsifying tank via a pipeline; the silicone oil storage tank is connected to the centrifuge via a pipeline; and the centrifuge is connected to the water quality conditioning tank via a pipeline.

[0011] Furthermore, the reflux structure includes a linear module, an oil skimmer, and an oil scraper; the linear module is disposed on the upper part of the demulsification reaction tank, and a slider is slidably connected to the upper part of the linear module; the oil skimmer is fixedly connected to the upper side of the slider on the upper part of the linear module; and the oil scraper is fixedly connected to the lower part of the oil skimmer.

[0012] Furthermore, the reflux structure also includes a sludge conveying pipe and a mixed liquor conveying pipe; the sludge conveying pipe is fixedly connected to the middle of the limiting mounting box; the mixed liquor conveying pipe is fixedly connected to the front side of the limiting mounting box.

[0013] Furthermore, the reflux structure also includes a mixed liquor reflux pump and a sludge reflux pump; the input end of the mixed liquor reflux pump is connected to the mixed liquor delivery pipe through a pipeline, and the output end of the mixed liquor reflux pump is connected to the anoxic denitrification zone of the integrated reactor through a pipeline; the input end of the sludge reflux pump is connected to the sludge delivery pipe through a pipeline, and the output end of the sludge reflux pump is connected to the anaerobic hydrolysis zone of the integrated reactor through a pipeline.

[0014] Furthermore, the reflux structure also includes a blower mounting box, an airflow collection box, and an oil collection tank; the airflow collection box is fixedly connected to the inner side of the integrated reactor; the blower mounting box is fixedly connected to the front side of the positioning mounting frame, and an aeration blower is installed inside the blower mounting box; the blower mounting box is connected to the airflow collection box via a pipe; the airflow collection box is connected to the microporous aeration element via a pipe; the oil collection tank is fixedly connected to the inner side of the demulsification reaction tank, and the oil collection tank is connected to the pipe connecting the demulsification reaction tank to the heating demulsification tank.

[0015] Beneficial effects This invention employs a comprehensive reactor, divided into aerobic degradation, anoxic denitrification, and anaerobic hydrolysis zones by multiple baffles. The membrane module support is directly bolted to the aerobic degradation zone, suspending the membrane module and achieving in-situ coupling of biodegradation and membrane separation. This avoids transferring wastewater between the bioreactor and membrane separation zones via pipelines, effectively shortening the overall wastewater treatment process, saving significant time, and improving treatment efficiency. It also prevents sludge settling and silicone oil re-emulsification during wastewater transfer, reducing the risk of membrane fouling and extending membrane module lifespan. A reciprocating self-locking drive in the water quality equalization tank rotates the agitator, ensuring more uniform pH adjustment and stable operation of subsequent treatment processes. A demulsification tank with settling ramps enables initial sludge settling. The coordinated setup of the heated demulsification tank, centrifuge, and silicone oil storage tank not only efficiently separates silicone oil from wastewater for resource recovery but also allows the residual liquid after centrifugation to be recycled. The water quality equalization tank re-treats the wastewater, enabling its reuse and reducing resource waste. The combination of the chemical washing tank, backwash pump, and water collection pipe allows for timely and effective backwashing and maintenance of the membrane module, ensuring the continuity of membrane separation performance. The mixed liquor return pump and sludge return pump transport the mixed liquor and sludge to the anoxic denitrification zone and anaerobic hydrolysis zone of the integrated reactor, respectively, realizing the recycling of sludge and mixed liquor, maintaining the stability of the microbial community in the reactor, and improving the efficiency of biodegradation. The linkage of the blower mounting box, airflow collection box, and microporous aerator provides uniform and sufficient aeration to the integrated reactor, ensuring the degradation effect in the aerobic degradation zone. At the same time, the airflow generated by aeration can also purge the membrane module, reducing the adsorption of pollutants on the membrane surface and further reducing the probability of membrane fouling. The combination of the linear module, oil skimmer, and oil scraper can efficiently collect the floating oil in the demulsification reaction tank and guide it into the oil collection tank, and then transport it to the heated demulsification tank for subsequent treatment, improving the efficiency of oil-water separation and preventing floating oil from entering subsequent treatment stages and affecting the treatment effect. Attached Figure Description

[0016] To more clearly illustrate the technical solutions of the embodiments of the present invention, the accompanying drawings of the embodiments will be briefly described below.

[0017] The accompanying drawings described below are only related to some embodiments of the invention and are not intended to limit the invention.

[0018] In the attached diagram: Figure 1 This is a schematic diagram of the overall structure of the present invention.

[0019] Figure 2 This is a schematic diagram showing the positional relationship between the integrated reactor, the water quality conditioning tank, and the reciprocating self-locking drive component of this invention.

[0020] Figure 3This is a schematic diagram showing the positional relationship between the integrated reactor, chemical washing tank, backwash pump, and product water pump of this invention.

[0021] Figure 4 This is a schematic diagram showing the positional relationship between the integrated reactor, the blower mounting box, and the mixed liquid return pump of this invention.

[0022] Figure 5 This is a schematic diagram showing the positional relationship between the demulsification reaction tank, oil collection tank, linear module, and oil skimmer of the present invention.

[0023] Figure 6 This is a schematic diagram showing the positional relationship between the integrated reactor, the flow guide baffle, and the membrane module support of the present invention.

[0024] Figure 7 This is a schematic diagram showing the positional relationship between the membrane module support, the limiting mounting box, and the microporous aeration element of the present invention.

[0025] Figure 8 This is a schematic diagram showing the positional relationship between the limiting installation box, microporous aeration component, water collection pipe, sludge conveying pipe, and mixed liquor conveying pipe of the present invention.

[0026] List of reference numerals 1. Positioning mounting frame; 101. Chemical washing tank; 102. Blower mounting box; 103. Backwash pump; 104. Product water pump; 2. Integrated reactor; 201. Mixed liquor return pump; 202. Sludge return pump; 203. Airflow collection box; 204. Water quality conditioning tank; 205. Reciprocating self-locking drive component; 206. Agitator; 207. Demulsification reaction tank; 208. Oil collection tank; 209. Linear module; 210. Oil skimmer; 211. Oil scraper; 212. Heated demulsification tank; 213. Centrifuge; 214. Silicone oil storage tank; 3. Flow guide baffle; 4. Membrane module support; 5. Limiting mounting box; 501. Water collection pipe; 502. Sludge conveying pipe; 503. Mixed liquor conveying pipe; 6. Microporous aerator. Detailed Implementation

[0027] Example 1: Please refer to Figures 1 to 5 As shown: This invention provides a wastewater treatment device and process for simultaneous membrane separation and biodegradation cycle, comprising a positioning mounting frame 1, a comprehensive reactor 2, flow guide baffles 3, a treatment structure, a membrane module support 4, a limiting mounting box 5, and a microporous aerator 6; the comprehensive reactor 2 is located in front of the positioning mounting frame 1; multiple flow guide baffles 3 are provided, and the multiple flow guide baffles 3 are evenly distributed and fixedly connected to the inner side of the comprehensive reactor 2, dividing the comprehensive reactor 2 into an aerobic degradation zone, an anoxic denitrification zone, and an anaerobic hydrolysis zone; the treatment structure is located to the left of the comprehensive reactor 2; the membrane module support 4 is bolted to the aerobic degradation zone inside the comprehensive reactor 2, and multiple membrane modules are evenly distributed and suspended on the upper part of the membrane module support 4; the limiting mounting box 5 is fixedly connected to the lower part of the comprehensive reactor 2; and the microporous aerator 6 is fixedly connected to the inner side of the limiting mounting box 5.

[0028] The processing structure includes a chemical washing tank 101, a backwash pump 103, and a product water pump 104. The chemical washing tank 101 is fixedly connected to the upper part of the positioning mounting frame 1. The backwash pump 103 is bolted to the upper part of the chemical washing tank 101, and the input end of the backwash pump 103 is connected to the chemical washing tank 101. The product water pump 104 is bolted to the upper part of the chemical washing tank 101.

[0029] The treatment structure also includes a water quality conditioning tank 204, a water collection pipe 501, and a demulsification reaction tank 207. The water quality conditioning tank 204 is connected to the integrated reactor 2 via a pipe. The water collection pipe 501 is fixedly connected to the lower part of the integrated reactor 2, and the input end of the product water pump 104 is fixedly connected to the water collection pipe 501. A booster pump is installed at the upper part of the water quality conditioning tank 204. The input end of the booster pump is connected to the water quality conditioning tank 204, and the output end of the booster pump is connected to the demulsification reaction tank 207 via a pipe. A settling inclined plate is installed at the upper part of the demulsification reaction tank 207.

[0030] The processing structure also includes a reciprocating self-locking drive 205 and a stirring paddle 206; the reciprocating self-locking drive 205 is bolted to the upper part of the water quality conditioning tank 204; the stirring paddle 206 is rotatably connected to the middle part of the water quality conditioning tank 204, and the stirring paddle 206 is coaxially fixedly connected to the output end of the reciprocating self-locking drive 205.

[0031] The processing structure also includes a heated demulsifying tank 212, a centrifuge 213, and a silicone oil storage tank 214; the heated demulsifying tank 212 is connected to the demulsifying reaction tank 207 via a pipeline; the centrifuge 213 is connected to the heated demulsifying tank 212 via a pipeline; the silicone oil storage tank 214 is connected to the centrifuge 213 via a pipeline, and the centrifuge 213 is connected to the water quality conditioning tank 204 via a pipeline.

[0032] The specific usage and function of this embodiment are as follows: Silicone oil production wastewater is quantitatively introduced into the water quality equalization tank 204. The reciprocating self-locking drive component 205 is activated to drive the stirring paddle 206 to rotate at a uniform speed, thoroughly mixing the wastewater in the tank. This ensures the pH adjuster is evenly integrated with the wastewater, guaranteeing the accuracy and uniformity of the pH adjustment and laying a stable water quality foundation for subsequent treatment processes. After equalization, the wastewater is pressurized by a booster pump and then transported through a sealed pipeline to the demulsification reaction tank 207. The settling inclined plate inside the tank utilizes the principle of gravity settling to initially separate suspended sludge in the wastewater, reducing the load on subsequent treatment. Oily wastewater is transported through a dedicated pipeline to the heated demulsification tank 212. The clarified liquid after initial settling then enters the integrated reactor 2 through another pipeline for further treatment. Demulsifier is added to the heated demulsification tank 212, and heating is applied to efficiently separate floating oil and emulsified oil in the wastewater, completing the demulsification process. The material is transported to the centrifuge 213 through pipelines, where water and silicone oil are efficiently separated by high-speed centrifugation. The separated pure silicone oil is collected and recycled in the silicone oil storage tank 214, realizing resource reuse. The residual liquid after centrifugation flows back to the water quality conditioning tank 204 through the return pipeline for further recycling. If membrane fouling occurs after the membrane module has been used for a period of time, the backwash pump 103 is started to extract the cleaning solution in the chemical washing tank 101 and accurately introduce it into the membrane module area of ​​the integrated reactor 2 through the water collection pipe 501 for comprehensive online backwashing maintenance of the membrane module. The aerobic degradation zone of the integrated reactor 2 efficiently degrades organic pollutants in the wastewater through the metabolic action of microorganisms. The membrane module accurately intercepts and separates solid impurities such as sludge and macromolecular organic matter in the degraded wastewater. Finally, the purified water separated by the membrane module is pumped into the chemical washing tank 101 for temporary storage through the water collection pipe 501 by the product water pump 104.

[0033] Example 2: like Figures 5 to 8 As shown: Based on Embodiment 1, a reflux structure is also included; the reflux structure is disposed on the upper part of the positioning mounting bracket 1.

[0034] The reflux structure includes a linear module 209, an oil skimmer 210, and an oil skimmer 211. The linear module 209 is located on the upper part of the demulsification reaction tank 207, and a slider is slidably connected to the upper part of the linear module 209. The oil skimmer 210 is fixedly connected to the upper side of the slider on the upper part of the linear module 209. The oil skimmer 211 is fixedly connected to the lower part of the oil skimmer 210.

[0035] The reflux structure also includes a sludge conveying pipe 502 and a mixed liquor conveying pipe 503; the sludge conveying pipe 502 is fixedly connected to the middle of the limiting installation box 5; the mixed liquor conveying pipe 503 is fixedly connected to the front side of the limiting installation box 5.

[0036] The reflux structure also includes a mixed liquor reflux pump 201 and a sludge reflux pump 202. The input end of the mixed liquor reflux pump 201 is connected to the mixed liquor delivery pipe 503 through a pipe, and the output end of the mixed liquor reflux pump 201 is connected to the anoxic denitrification zone of the integrated reactor 2 through a pipe. The input end of the sludge reflux pump 202 is connected to the sludge delivery pipe 502 through a pipe, and the output end of the sludge reflux pump 202 is connected to the anaerobic hydrolysis zone of the integrated reactor 2 through a pipe.

[0037] The reflux structure also includes a blower mounting box 102, an airflow collection box 203, and an oil collection tank 208. The airflow collection box 203 is fixedly connected to the inside of the integrated reactor 2. The blower mounting box 102 is fixedly connected to the front of the positioning mounting frame 1. An aeration blower is installed inside the blower mounting box 102. The blower mounting box 102 is connected to the airflow collection box 203 through a pipe. The airflow collection box 203 is connected to the microporous aeration element 6 through a pipe. The oil collection tank 208 is fixedly connected to the inside of the demulsification reaction tank 207. The oil collection tank 208 is connected to the demulsification reaction tank 207 through a pipe that connects to the heating demulsification tank 212.

[0038] The specific usage and function of this embodiment are as follows: The separated sludge enters the anaerobic hydrolysis zone through the sludge return pump 202 along the sludge conveying pipe 502. The mixed liquor enters the anoxic denitrification zone through the mixed liquor return pump 201 along the mixed liquor conveying pipe 503. The airflow generated by the aeration blower can enter the airflow collection box 203 from the blower mounting box 102 along the pipeline, and then enter the microporous aeration element 6 along the pipeline. The oil scraper 211 can slide along the straight module 209 to collect the oil on the surface of the wastewater in the demulsification reaction tank 207, push the oil into the oil collection tank 208, and enter the heated demulsification tank 212 through the pipeline. All pipelines are equipped with check valves and regulating valves.

[0039] The following points should be noted in this article: 1. The accompanying drawings of this embodiment only involve the structures involved in this embodiment; other structures can refer to the general design.

[0040] 2. Where there is no conflict, this embodiment and the features in the embodiment can be combined with each other to obtain new embodiments.

[0041] The above are merely specific embodiments of the present invention, but the scope of protection of the present invention is not limited thereto. Any variations or substitutions that can be easily conceived by those skilled in the art within the technical scope disclosed in the present invention should be included within the scope of protection of the present invention. Therefore, the scope of protection of the present invention should be determined by the scope of the claims.

Claims

1. A wastewater treatment device with membrane separation and simultaneous biodegradation cycle, comprising a positioning mounting frame (1), a comprehensive reactor (2), a flow guide baffle (3), a treatment structure, a reflux structure, a membrane module support (4), a limiting mounting box (5), and a microporous aeration element (6); wherein the comprehensive reactor (2) is disposed on the front side of the positioning mounting frame (1); characterized in that: Multiple flow guide baffles (3) are provided, and the multiple flow guide baffles (3) are evenly distributed and fixedly connected to the inner side of the integrated reactor (2). The multiple flow guide baffles (3) divide the integrated reactor (2) into an aerobic degradation zone, an anoxic denitrification zone, and an anaerobic hydrolysis zone. The treatment structure is located on the left side of the integrated reactor (2). The membrane module support (4) is bolted to the aerobic degradation zone inside the integrated reactor (2), and multiple membrane modules are evenly distributed and suspended on the upper part of the membrane module support (4). The limiting installation box (5) is fixedly connected to the lower part of the integrated reactor (2). The microporous aeration element (6) is fixedly connected to the inner side of the limiting installation box (5). The reflux structure is located on the upper part of the positioning installation frame (1).

2. The wastewater treatment device with membrane separation and simultaneous biodegradation cycle as described in claim 1, characterized in that: The processing structure includes a chemical washing tank (101), a backwash pump (103), and a product water pump (104); the chemical washing tank (101) is fixedly connected to the upper part of the positioning mounting frame (1); the backwash pump (103) is bolted to the upper part of the chemical washing tank (101), and the input end of the backwash pump (103) is connected to the chemical washing tank (101); the product water pump (104) is bolted to the upper part of the chemical washing tank (101).

3. The wastewater treatment device with membrane separation and simultaneous biodegradation cycle as described in claim 2, characterized in that: The treatment structure also includes a water quality conditioning tank (204), a water collection pipe (501), and a demulsification reaction tank (207); the water quality conditioning tank (204) is connected to the integrated reactor (2) through a pipe; the water collection pipe (501) is fixedly connected to the lower part of the integrated reactor (2), and the input end of the product water pump (104) is fixedly connected to the water collection pipe (501); a booster pump is provided at the upper part of the water quality conditioning tank (204), the input end of the booster pump is connected to the water quality conditioning tank (204), and the output end of the booster pump is connected to the demulsification reaction tank (207) through a pipe; a settling inclined plate is provided at the upper part of the demulsification reaction tank (207).

4. The wastewater treatment device with membrane separation and simultaneous biodegradation cycle as described in claim 3, characterized in that: The processing structure also includes a reciprocating self-locking drive (205) and a stirring paddle (206); the reciprocating self-locking drive (205) is bolted to the upper part of the water quality conditioning tank (204); the stirring paddle (206) is rotatably connected to the middle part of the water quality conditioning tank (204), and the stirring paddle (206) is coaxially fixedly connected to the output end of the reciprocating self-locking drive (205).

5. The wastewater treatment device with membrane separation and simultaneous biodegradation cycle as described in claim 4, characterized in that: The processing structure also includes a heated demulsifying tank (212), a centrifuge (213), and a silicone oil storage tank (214); the heated demulsifying tank (212) is connected to the demulsifying reaction tank (207) via a pipeline; the centrifuge (213) is connected to the heated demulsifying tank (212) via a pipeline; the silicone oil storage tank (214) is connected to the centrifuge (213) via a pipeline, and the centrifuge (213) is connected to the water quality conditioning tank (204) via a pipeline.

6. The wastewater treatment device with membrane separation and simultaneous biodegradation cycle as described in claim 1, characterized in that: The reflux structure includes a linear module (209), an oil skimmer (210), and an oil skimmer (211); the linear module (209) is located on the upper part of the demulsification reaction tank (207), and a slider is slidably connected to the upper part of the linear module (209); the oil skimmer (210) is fixedly connected to the upper side of the upper slider of the linear module (209); and the oil skimmer (211) is fixedly connected to the lower part of the oil skimmer (210).

7. The wastewater treatment device with membrane separation and simultaneous biodegradation cycle as described in claim 6, characterized in that: The reflux structure also includes a sludge conveying pipe (502) and a mixed liquor conveying pipe (503); the sludge conveying pipe (502) is fixedly connected to the middle of the limiting installation box (5); the mixed liquor conveying pipe (503) is fixedly connected to the front side of the limiting installation box (5).

8. The wastewater treatment device with membrane separation and simultaneous biodegradation cycle as described in claim 7, characterized in that: The reflux structure also includes a mixed liquor reflux pump (201) and a sludge reflux pump (202); the input end of the mixed liquor reflux pump (201) is connected to the mixed liquor delivery pipe (503) through a pipe, and the output end of the mixed liquor reflux pump (201) is connected to the anoxic denitrification zone of the integrated reactor (2) through a pipe; the input end of the sludge reflux pump (202) is connected to the sludge delivery pipe (502) through a pipe, and the output end of the sludge reflux pump (202) is connected to the anaerobic hydrolysis zone of the integrated reactor (2) through a pipe.

9. The wastewater treatment device with membrane separation and simultaneous biodegradation cycle as described in claim 8, characterized in that: The reflux structure also includes a blower mounting box (102), an airflow collection box (203), and an oil collection tank (208); the airflow collection box (203) is fixedly connected to the inner side of the integrated reactor (2); the blower mounting box (102) is fixedly connected to the front side of the positioning mounting frame (1), and an aeration blower is installed on the inner side of the blower mounting box (102). The blower mounting box (102) is connected to the airflow collection box (203) through a pipe; the airflow collection box (203) is connected to the microporous aeration element (6) through a pipe; the oil collection tank (208) is fixedly connected to the inner side of the demulsification reaction tank (207), and the oil collection tank (208) is connected to the demulsification reaction tank (207) through a pipe connecting the heating demulsification tank (212).

10. The wastewater treatment process of membrane separation and simultaneous biodegradation cycle as described in claims 1-9, characterized in that: S1. The silicone oil production wastewater is introduced into the water quality conditioning tank. The reciprocating self-locking drive unit drives the stirring paddle to rotate and stir the wastewater, and simultaneously completes the uniform adjustment of the pH value of the wastewater. After the adjustment is completed, it is temporarily stored in the water quality conditioning tank. S2. The conditioned wastewater in the water quality conditioning tank is transported to the demulsification reaction tank by a booster pump. The sludge in the wastewater is initially settled by the settling inclined plate in the tank. At the same time, the oil skimmer and oil skimmer are moved by the linear module to collect the floating oil on the surface of the wastewater and introduce it into the oil collection tank. The settled wastewater and the floating oil collected in the oil collection tank are transported through pipelines respectively. S3. The floating oil and oily wastewater conveyed by the demulsification reaction tank are introduced into the heating demulsification tank for heating demulsification treatment. After demulsification, the material is conveyed to the centrifuge for solid-liquid-oil three-phase separation. The separated silicone oil is introduced into the silicone oil storage tank for collection. The residual liquid after centrifugation is returned to the water quality conditioning tank for further treatment. S4. The wastewater after initial settling in the demulsification reaction tank is transported to the integrated reactor. The wastewater flows sequentially through the anaerobic hydrolysis zone, the anoxic denitrification zone, and the aerobic degradation zone in the integrated reactor to complete the stepwise biodegradation of organic pollutants in the wastewater. In the aerobic degradation zone, the degraded wastewater is simultaneously separated by membrane modules suspended on the membrane module support to achieve efficient retention of sludge, macromolecular organic matter, siloxanes, and suspended solids. S5. Airflow is generated by the aeration blower in the blower installation box. After being evenly distributed by the airflow collection box, the airflow is released into the integrated reactor through the microporous aeration element. This provides an aeration environment for the aerobic degradation zone and at the same time, the airflow is used to sweep the surface of the membrane module to reduce pollutant adsorption. S6. The sludge retained by membrane separation is returned to the anaerobic hydrolysis zone of the integrated reactor via the sludge return pump and the mixed liquor is returned to the anoxic denitrification zone of the integrated reactor via the mixed liquor return pump and the mixed liquor is returned to the anoxic denitrification zone of the integrated reactor via the mixed liquor return pump, so as to maintain the stability of the microbial community and high sludge concentration in the reactor. S7. The purified permeate after membrane separation is collected through a water collection pipe by a permeate pump to complete the treatment of silicone oil production wastewater. The cleaning solution in the chemical washing tank is periodically transported to the membrane module through a water collection pipe by a backwash pump to perform online backwashing maintenance on the membrane module.