一种高耐热酚醛树脂及其制备方法

By pre-modifying phenol and using melamine and formaldehyde to form a modified phenol intermediate, a high cross-linking density benzene ring-triazine ring synergistic network structure is constructed, which solves the problems of thermal stability and insufficient cross-linking network of phenolic resin under high temperature and high load conditions, and achieves a significant improvement in the high temperature stability and ablation resistance of the material.

CN122145739BActive Publication Date: 2026-07-17CHANGSHU SOUTHEAST PLASTIC CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CHANGSHU SOUTHEAST PLASTIC CO LTD
Filing Date
2026-05-06
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing phenolic resins lack sufficient thermal stability and cross-linked network structure under high temperature and high load conditions, resulting in poor stability and ablation resistance of the materials during long-term service.

Method used

By pre-modifying phenol, a modified phenol intermediate is formed by melamine and formaldehyde. Subsequently, the intermediate is polycondensed under acid catalysis and subjected to depressurized devolatilization to construct a three-dimensional network structure with high cross-linking density of benzene ring-triazine ring synergy.

Benefits of technology

It significantly improved the thermal decomposition temperature, glass transition temperature, char residue, and mechanical strength of phenolic resin, and enhanced the stability and ablation resistance of the material under high temperature and high load conditions.

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Abstract

本发明公开了一种高耐热酚醛树脂及其制备方法。该方法包括:先将苯酚与三聚氰胺在甲醛存在下于60~90℃预反应1~3h形成改性苯酚中间体;再与甲醛在酸性催化剂作用下于75~100℃缩聚1~4h;升温至110~150℃继续反应2~4h;最后经常压脱水及130~180℃、5000~10000Pa减压脱挥,得到目标树脂。其中苯酚、三聚氰胺与甲醛摩尔比为1:(0.1~0.6):(0.2~0.8)。本发明通过三嗪环预嵌入构建高交联密度耐热网络,使树脂Tmax达412~462℃,Tg达168~215℃,800℃残炭率达58.3~73.5%,显著提升热稳定性、抗热氧化性和力学性能,适用于高温摩擦材料领域。
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