一种含有嵌入式Fe3O4 / BN复合填料的导热环氧树脂膜、该复合填料及应用

By embedding Fe3O4/BN composite filler in boron nitride sheets and using magnetic field-induced orientation, the problem of insufficient vertical thermal conductivity of boron nitride in polymer-based thermal conductive materials is solved, achieving high-efficiency thermal conductivity and stable dielectric properties, making it suitable for heat dissipation of high-power electronic devices.

CN122145980BActive Publication Date: 2026-07-17南京红太阳医药研究院有限公司 +2

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
南京红太阳医药研究院有限公司
Filing Date
2026-05-08
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Among existing polymer-based thermally conductive materials, boron nitride has a vertical thermal conductivity (out-of-plane thermal conductivity) that is much lower than its in-plane thermal conductivity. Furthermore, magnetic field induction technology is insufficient in terms of orientation capability and stability, making it difficult to balance magnetic responsiveness and thermal conductivity.

Method used

By preparing embedded Fe3O4/BN composite fillers, Fe/Fe3C particles are embedded in boron nitride sheets through high-temperature pyrolysis and oxidation treatment, and then converted into Fe3O4. Combined with orientation induced by an external magnetic field, a thermally conductive network that penetrates the thickness is constructed.

Benefits of technology

It significantly improves the out-of-plane thermal conductivity of composite materials, enhances the stability and dielectric properties of the materials, meets the heat dissipation requirements of high-power electronic devices, and achieves synergistic optimization of thermal conductivity and mechanical properties.

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Abstract

本发明公开了一种含有嵌入式Fe3O4 / BN复合填料的导热环氧树脂膜、该复合填料及应用,属于高分子复合材料与热管理技术领域。该方法通过含铁前驱体高温热解可控氧化法,在形成氮化硼的同时在氮化硼内部和边缘均匀嵌入四氧化三铁纳米颗粒;将该填料分散于聚合物基体中,在外加磁场作用下,利用Fe3O4的磁响应性诱导BN填料发生取向排列,最终获得具有高导热系数的聚合物复合材料。本发明克服了传统方法中填料取向不可控、导热性能重复性差的弊端。所得导热环氧树脂膜在电子封装、热界面材料等领域具有广阔的应用前景。
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