一种用于农田土壤重金属钝化的有机-无机复合修复材料及其制备方法

By preparing calcium hydroxyphosphate-loaded LDH powder and forming gel microspheres, the stability and dust problems of existing soil heavy metal passivation materials were solved, achieving efficient and safe soil heavy metal passivation.

CN122146309BActive Publication Date: 2026-07-17SINO-SINGAPORE RUIMEI (TIANJIN) ENVIRONMENTAL PROTECTION TECH CO LTD +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SINO-SINGAPORE RUIMEI (TIANJIN) ENVIRONMENTAL PROTECTION TECH CO LTD
Filing Date
2026-05-09
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing soil heavy metal passivation materials are insufficient in terms of long-term stability and mechanical strength, making it difficult to effectively fix heavy metals. Furthermore, powdered materials are prone to causing dust when used in farmland.

Method used

Layered bimetallic hydroxide (LDH) was used as a carrier to load hydroxyapatite via co-precipitation reaction, and sodium alginate was modified with citric acid to form gel microspheres. Combined with calcium-aluminum crosslinking, an organic-inorganic composite repair material was prepared to improve the stability and mechanical strength of the material.

Benefits of technology

It achieves efficient and long-lasting fixation of heavy metals, reduces dust emissions, improves ease of use and safety, and provides a more durable soil remediation effect.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明属于土壤修复技术领域,涉及一种用于农田土壤重金属钝化的有机‑无机复合修复材料及其制备方法,包括:将镁盐和铝盐溶于去离子水中,得到混合盐溶液;将氢氧化钠溶液滴入混合盐溶液中,滴加完毕后加热反应,得到LDH浆液;向LDH浆液中加入去离子水,得到LDH分散液;向LDH分散液中同时滴加氯化钙溶液和磷酸氢二钠溶液,滴加过程中滴加碱液调节pH值,滴加完毕后加热反应,得到羟基磷酸钙负载LDH粉末;将柠檬酸加入海藻酸钠溶液中进行反应,得到改性海藻酸钠溶液;将羟基磷酸钙负载LDH粉末分散于改性海藻酸钠溶液中,得到悬浮液;将氯化钙溶液和氯化铝溶液混合,得到交联液;将悬浮液滴入交联液中交联固化,烘干后得到有机‑无机复合修复材料。
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