一种基于石墨烯的自支撑GaN衬底的制备方法

By using graphene layer patterning and vapor deposition, non-destructive separation of GaN epitaxial layers from the substrate was achieved, solving the problem of strong interfacial adhesion and improving the growth quality and production efficiency of self-supporting GaN substrates.

CN122147517BActive Publication Date: 2026-07-17SUZHOU UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SUZHOU UNIV
Filing Date
2026-05-06
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing technologies, the interface bonding between the GaN epitaxial layer and the substrate is strong, making it difficult to achieve non-destructive peeling and easily introducing damage and defects, which affects the improvement of device performance.

Method used

The graphene layer is patterned to form window and mask regions. Combined with metal-organic chemical vapor deposition and hydride vapor phase epitaxy, the GaN substrate is non-destructively peeled off from the substrate by weak van der Waals forces, avoiding laser, chemical etching or mechanical force.

Benefits of technology

This technology enables non-destructive peeling of high-quality self-supporting GaN substrates, reducing production costs, improving growth quality and production efficiency, ensuring a smooth and crack-free surface, and reducing defect density.

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Abstract

本申请公开了一种基于石墨烯的自支撑GaN衬底的制备方法,涉及半导体器件技术领域。制备方法包括:对衬底层上的石墨烯层进行图形化处理,制备获得具有间隔布置的多个窗口区域的石墨烯掩膜区域;利用金属有机化学气相沉积工艺在石墨烯掩膜区域中沉积GaN薄膜,直至窗口区域的GaN薄膜与衬底层形成空隙;利用氢化物气相外延工艺在GaN薄膜上沉积GaN膜层,并在剥离处理后获得自支撑GaN衬底;其中,成核生长阶段的温度为550℃‑600℃,退火结晶阶段的温度为1050℃‑1100℃。本申请实现了在保证GaN外延层高质量生长的同时显著降低其与衬底之间的界面结合强度,从而能够实现无损剥离并获得高质量自支撑GaN衬底。
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