一种Li2C2O4包覆FeTiO3阳极材料及其制备方法与应用

By coating the FeTiO3 anode material with Li2C2O4 to form a stable SEI film, the problems of lithium loss and poor cycle stability in lithium-ion batteries are solved, and high energy density and long cycle life lithium-ion battery performance are achieved.

CN122158553BActive Publication Date: 2026-07-17INNER MONGOLIA UNIV OF TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
INNER MONGOLIA UNIV OF TECH
Filing Date
2026-04-29
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing lithium-ion batteries, FeTiO3 anode materials suffer from severe lithium loss, unstable SEI film, low capacity, and poor cycle stability during cycling, which are difficult to effectively solve using traditional coating methods.

Method used

The preparation method of FeTiO3 anode material using Li2C2O4 coating involves coating the FeTiO3 surface with Li2C2O4 to form a dense and stable SEI film, thereby constructing a lithium-ion transport channel, compensating for lithium loss, and improving the lithium storage capacity of the material.

Benefits of technology

It significantly improves the initial capacity and cycle stability of the anode material, reduces the degree of polarization, improves ionic conductivity and energy density, suppresses material deactivation and lattice volume expansion, and simplifies the preparation process.

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Abstract

本发明公开一种Li2C2O4包覆FeTiO3阳极材料及其制备方法与应用,制备方法为:步骤1、制备FeTiO3粉末;步骤2、将Li2C2O4粉末溶解在由去离子水和无水乙醇按体积比为(6~8):3组成的混合溶剂中,超声后放入水浴锅中搅拌,加入PVP,混合均匀后得Li2C2O4溶液;步骤3、向Li2C2O4溶液中加FeTiO3粉末,部分溶剂蒸发使Li2C2O4析出附着在FeTiO3粉末表面,固液分离后将得到的包覆产物洗涤、干燥,得到Li2C2O4包覆FeTiO3阳极材料。本发明Li2C2O4的引入补偿了首次SEI膜形成过程中的锂损失,构建起锂离子传输通道,首次充电阴极的锂离子能够更易到达负极发生反应,大幅提升电极材料的初始容量。同时包覆架构在其表面形成保护层,抑制电极材料循环过程中的失活现象,弥补材料容量低的缺陷,提高材料本身的储锂能力。
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