一种热冲击诱导催化电极、制备方法及其废水处理应用

The thermal shock induced catalytic electrode prepared by laser shock strengthening and annealing quenching process solves the problem of the imbalance between catalytic activity and stability of mixed metal oxide electrodes in water treatment, and achieves the effect of efficient removal of refractory organic pollutants, which is suitable for large-scale industrial production.

CN122166897BActive Publication Date: 2026-07-17SUN YAT SEN UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SUN YAT SEN UNIV
Filing Date
2026-05-12
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing mixed metal oxide electrodes suffer from an imbalance between catalytic activity, conductivity, and stability in water treatment, and their preparation process is complex, making it difficult to achieve large-scale industrial application.

Method used

A thermally shock-induced catalytic electrode was prepared by loading a mixed metal oxide solid solution with laser shock strengthening treatment combined with the dip-coating-space slope flow method, and then preparing it through annealing, quenching and tempering processes. This process controlled the mesoscale surface structure and macroscale porous structure, thereby improving catalytic activity and conductivity.

Benefits of technology

The prepared catalytic electrode has a high specific surface area and abundant active sites, which significantly improves the efficiency of electrocatalytic oxidation reaction, can efficiently remove recalcitrant organic pollutants, and the preparation process is simple and easy to industrialize.

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Abstract

本发明公开了一种热冲击诱导催化电极、制备方法及其废水处理应用,属于废水处理技术领域。催化电极包括钛金属基底以及形成于所述钛金属基底表面的混合金属氧化物催化层;混合金属氧化物催化层具有富羟基化表面、高比表面积和大孔容,其微观结构为含有纳米级晶粒的均匀泥裂状多孔结构。其制备方法包括先对钛金属基底进行激光冲击强化以形成介尺度阵列结构;接着采用浸渍提拉‑空间坡流法负载混合金属氧化物前驱体;随后进行退火处理;将退火后的电极迅速浸入过氧化氢溶液中实施热冲击淬火,最后进行低温回火以消除内应力、降低电阻。本发明的催化电极可兼顾催化活性、导电性与稳定性平衡,且制备工艺简单、易于工业化大规模生产。
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