一种高强度硬质合金材料及其制备方法

By combining cobalt powder, tungsten carbide powder, reinforcing components, and refining agents, the problem of grain growth during the sintering process of nano-WC-Co cemented carbide was solved, achieving high strength and high toughness of the cemented carbide and improving its overall performance.

CN122168959BActive Publication Date: 2026-07-17PENG TUNGSTEN ALLOY (SHANDONG) CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
PENG TUNGSTEN ALLOY (SHANDONG) CO LTD
Filing Date
2026-05-13
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

During the sintering process, the grains of nano-WC-Co cemented carbide tend to grow, leading to a decline in performance. Existing technologies that add nano-sized vanadium carbide reduce the ability of the cobalt phase to wet tungsten carbide, thus affecting mechanical properties.

Method used

By combining cobalt powder, tungsten carbide powder, reinforcing components, and refining agents, and through ball milling, spray granulation, compaction, and spark plasma sintering processes, combined with the use of materials such as aluminum dihydrogen phosphate, silica sol, cerium oxide, zirconium oxide, tantalum carbide, molybdenum carbide, and hydroxylated chromium oxide, a steric hindrance layer and chemical bonding are formed, refining the grains and improving the strength and toughness of cemented carbide.

Benefits of technology

It effectively inhibits tungsten carbide grain growth, improves the hardness, toughness, impact resistance and wear resistance of cemented carbide, and significantly enhances its overall performance.

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Abstract

本发明涉及硬质合金材料技术领域,具体公开了一种高强度硬质合金材料及其制备方法,包括以下重量份的原料:钴粉5‑8份、碳化钨粉86‑90份、增强组分2.4‑2.8份和改性细化剂0.5‑0.7份;所述高强度硬质合金材料的制备方法包括以下步骤:步骤S1、预混料的制备;步骤S2、喷雾制粒;步骤S3、压坯;步骤S4、放电等离子烧结。本发明加入了增强组分和改性细化剂,增强组分中含有磷酸二氢铝、硅溶胶、氧化铈、氧化锆、碳化钽、碳化钼和二氧化钛凝胶等组分,不仅自身具有优异的物性,还能与改性细化剂形成氢键作用,协同提高硬质合金材料的综合性能。
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