一种GO层间原位生长TiO2复合膜的制备方法与应用

By using a method of in-situ growth of TiO2 composite films between graphene oxide layers, near-infrared irradiation technology was used to achieve uniform dispersion of TiO2 nanoparticles, which solved the problems of insufficient structural stability and separation selectivity of graphene oxide films in seawater systems, and improved the separation performance and stability of the films.

CN122183402BActive Publication Date: 2026-07-17LANZHOU UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
LANZHOU UNIV
Filing Date
2026-05-15
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing technologies, graphene oxide membranes in seawater systems suffer from interlayer spacing fluctuations, structural stability degradation, and sensitivity to organic pollution, resulting in insufficient separation selectivity in systems where uranium/vanadium and other multi-metal ions coexist. Furthermore, existing modification methods suffer from high temperature and high energy consumption.

Method used

A method for preparing TiO2 composite films in situ grown between graphene oxide layers using near-infrared irradiation technology ensures that TiO2 nanoparticles are uniformly dispersed between layers and form well-crystallized TiO2 crystal domains through steps of preparing a titanium source, dispersion, film formation, and near-infrared irradiation.

Benefits of technology

It significantly improves the membrane's structural regularity and ion sieving performance, enhances the selective separation ability of uranyl ions and vanadium ions, and improves its resistance to organic fouling and long-term operational stability.

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Abstract

本发明涉及膜分离技术领域,具体为一种GO层间原位生长TiO2复合膜的制备方法与应用,GO层间原位生长TiO2复合膜的制备方法包括以下步骤:S1、制备钛源;S2、分散;S3、成膜;S4、近红外辐照。将GO层间原位生长TiO2复合膜装入渗透分离装置,使膜的一侧为海水,另一侧为去离子水,在常温和紫外光辐照条件下进行渗透分离,实现铀酰离子与钒酰离子的选择性分离。本发明通过近红外辐照技术实现了二氧化钛纳米颗粒在GO层间的原位生长,确保了颗粒在层间通道中的均匀分散,显著提升了膜的结构规整性和离子筛分性能,进而大幅增强了膜在海水中对铀酰离子与钒酰离子的选择性分离能力、抗有机物污染性能以及长期运行稳定性。
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