油气田高温高盐储层缓蚀阻垢复合剂及其制备方法

The composite agent, composed of a four-arm branched water-soluble terpolymer and a long-chain alkyl imidazoline quaternary ammonium salt, solves the problems of insufficient temperature resistance and polymer instability of scale inhibitors under high temperature and high salt conditions in the existing technology, and achieves a highly efficient integrated scale inhibition and corrosion inhibition effect, meeting the long-term protection requirements of deep well injection and production systems.

CN122187270BActive Publication Date: 2026-07-17XI'AN PETROLEUM UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
XI'AN PETROLEUM UNIVERSITY
Filing Date
2026-05-12
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Under high temperature and high salinity coupled conditions, existing oilfield chemicals suffer from insufficient temperature resistance due to the β-fracture of the main chain in linear polymer scale inhibitors. Furthermore, the physical mixing of polymers and imidazoline corrosion inhibitors lacks synergistic effects, and the phosphonic acid group density is insufficient. Consequently, the polymers become unstable in high salinity media, making it impossible to achieve long-term scale and corrosion protection for deep well injection and production systems.

Method used

A composite agent composed of a four-arm branched water-soluble terpolymer and a long-chain alkyl imidazoline quaternary ammonium salt is used to form an ion-pair complex through coulombic interaction, forming a dense hydrophobic corrosion inhibitor film at the metal interface. The three-stage synergistic mechanism achieves integrated scale inhibition and corrosion inhibition, and the polymer remains stable under high temperature and high salt conditions.

Benefits of technology

Under operating conditions of 180°C and 200,000 mg/L, the composite agent achieves a scale inhibition rate of over 90% for CaCO3 and BaSO4, a corrosion inhibition rate of over 85% for carbon steel N80, and an integrated corrosion inhibition and scale inhibition synergy index of over 1.2, enabling 14 days of continuous protection for deep well injection and production systems.

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Abstract

本发明属于油田水处理药剂技术领域,具体涉及油气田高温高盐储层缓蚀阻垢复合剂及其制备方法,复合剂由质量比(2~5):1的支化型水溶性三元共聚物组分与长链烷基咪唑啉季铵盐组分构成,前者以多元醇硫醇酯为支化中心节点,由含羧基、磺酸基、膦酸基的三元单体共聚而成,支化度3~6,Mw3000~15000Da;后者为含C16‑C18直链烷基与季铵化N+位点的咪唑啉化合物,两组分通过库仑作用形成离子对复合体,在水相远场稳定凝聚、Fe界面近场解离、金属表面定向锚定,在180°C×200000mg / L苛刻工况下,CaCO3与BaSO4阻垢率均超过90%,N80缓蚀率超过85%,协效指数大于1.2。
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