一种直流偏压特性X7R陶瓷介质材料及其制备方法

By preparing core-shell barium titanate powder using an in-situ hydrothermal method and employing a segmented atmosphere sintering process, the stability and uniformity issues of X7R ceramic dielectric materials under DC bias were resolved. This resulted in high performance stability and low dielectric loss over a wide temperature range, meeting the application requirements of high-end MLCCs.

CN122187484BActive Publication Date: 2026-07-17HANGZHOU XINGRONG TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HANGZHOU XINGRONG TECH CO LTD
Filing Date
2026-05-18
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing X7R ceramic dielectric materials suffer from insufficient wide-temperature dielectric stability under DC bias, poor grain uniformity, and unclear core-shell structure, failing to meet the stringent performance requirements of high-end MLCCs.

Method used

Uniform core-shell barium titanate powder was prepared by in-situ hydrothermal method. A multi-component synergistic doping system and segmented atmosphere sintering process were adopted to achieve comprehensive optimization of DC bias stability, wide temperature capacitance variation, dielectric loss and sintering activity.

Benefits of technology

It achieves a capacity change rate of ≤±11% over a wide temperature range of -55℃ to 125℃, a stable dielectric constant of 2400~2600, a dielectric loss of ≤0.012, no temperature drift abrupt changes, and a capacity decay rate of less than 9% under DC bias, meeting the stringent application requirements of high-end MLCCs.

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Abstract

本发明公开了一种直流偏压特性X7R陶瓷介质材料及其制备方法,通过优化的两步原位水热工艺构筑均匀核壳结构钛酸钡主晶相,以高纯纳米BaTiO3为核、Dy3+掺杂BaTiO3为壳,配合稀土‑过渡金属多元掺杂、复配玻璃相与分段气氛烧结工艺,明确核壳结构抑制铁电畴翻转的微观机理及优化工艺的设计逻辑与效果,解决了传统X7R陶瓷核壳结构制备中分散不均、均相成核、杂相残留等技术难题。制备的X7R陶瓷材料兼具高偏压稳定性、宽温稳定性与高可靠性,具备极高的工程应用价值。
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