一种双掺杂尖晶石催化剂及其制备方法和应用

The preparation of dual-doped spinel catalysts by induction in a low-temperature eutectic medium solves the problems of high cost and insufficient stability of anolyte oxygen evolution catalysts, achieves efficient and stable catalysis in different electrolytes, reduces the amount of precious metals used, and improves the structural stability and activity of the catalyst.

CN122189747BActive Publication Date: 2026-07-17NANJING UNIV OF AERONAUTICS & ASTRONAUTICS

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
NANJING UNIV OF AERONAUTICS & ASTRONAUTICS
Filing Date
2026-05-15
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing water electrolysis hydrogen production technologies, the oxygen evolution catalyst at the anode relies on precious metals, which is costly and has slow reaction kinetics. Furthermore, the stability and activity of doped spinel catalysts in different electrolytes are insufficient, making it difficult to meet industrial requirements.

Method used

By employing a low-temperature eutectic medium to induce precursor oxide lattice reshaping, efficient and uniform implantation of noble and rare earth metals is achieved, thus preparing a dual-doped spinel catalyst. This process suppresses low-stability surface adsorption and metal cluster formation, thereby enhancing the catalyst's structural stability and activity.

Benefits of technology

It exhibits excellent corrosion resistance and high stability in different electrolytes, significantly reducing the amount of precious metals required. Its catalytic performance is superior to commercial IrO2, and it is suitable for acidic, alkaline, and seawater media, showing promising prospects for industrial applications.

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Abstract

本发明公开了一种双掺杂尖晶石催化剂及其制备方法和应用,属于电催化纳米材料制备技术领域,本发明包括:制备包含掺杂金属的前驱体氧化物;将所述前驱体氧化物与低温共熔介质混合;在低温下对混合物进行煅烧,通过所述低温共熔介质诱导所述前驱体氧化物发生晶格重塑,实现所述掺杂金属离子均一注入所述前驱体氧化物的体相晶格,得到所述掺杂尖晶石氧化物。本发明通过低温共熔介质诱导晶格重塑,实现掺杂金属离子高效均一注入体相晶格,有效抑制了低稳定性表面吸附单原子及低活性团簇的形成,显著提升了催化剂的结构稳定性与活性位点利用率,在电催化析氧反应中实现了低贵金属载量、高催化效率与长催化寿命的协同提升。
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