一种具有自修复功能膜的复合集流体的制备方法与应用

By constructing a keratin-polyethyleneimine self-healing functional film on the current collector surface of lithium-ion batteries, the problems of lithium dendrite growth and volume expansion were solved, achieving high mechanical strength and self-healing capability, extending battery life and reducing costs.

CN122202178BActive Publication Date: 2026-07-17CHENGDU TECH UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CHENGDU TECH UNIV
Filing Date
2026-05-14
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing lithium metal batteries face problems of severe volume expansion and uncontrollable growth of lithium dendrites during cycling. Existing protective layers cannot effectively block dendrite growth and lack self-repair capabilities, leading to rapid degradation of battery life.

Method used

A self-healing functional membrane was constructed on the surface of a current collector using a keratin-polyethyleneimine composite solution. The high-modulus rigid framework provided by the disulfide bonds within the keratin molecules and the flexible segments and hydrogen bond network of polyethyleneimine were utilized to achieve self-healing of the membrane and physical suppression of lithium dendrites.

Benefits of technology

It improves the long-cycle stability and mechanical strength of lithium-ion batteries, achieves self-healing function, extends battery life, and reduces costs by utilizing biomass waste.

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Abstract

本发明涉及一种具有自修复功能膜的复合集流体的制备方法与应用,属于锂离子电池技术领域。本发明的制备方法包括以下步骤:先配制角蛋白复合聚乙烯亚胺溶液,然后将配制好的角蛋白复合聚乙烯亚胺溶液滴加在铜箔表面,静置后水洗干燥,得到表面附着有高模量的具有自修复功能膜的铜集流体。本发明的制备方法制备的集流体既能通过高模量物理压制抑制枝晶生长,又能在表面产生裂纹时自动修复裂纹,提升电池循环寿命。
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