一种基于可控相变制备高性能氧化铝陶瓷的方法及所得氧化铝陶瓷

By introducing yttrium oxide into alumina ceramics and combining it with spark plasma sintering and heat treatment, residual compressive stress and dislocation networks are introduced into the alumina matrix through phase transformation reaction, which solves the problems of component segregation and interface weakening caused by the addition of multiple components and significantly improves the flexural strength of alumina ceramics.

CN122212693BActive Publication Date: 2026-07-17SHANDONG UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHANDONG UNIV
Filing Date
2026-05-14
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing alumina ceramics are prone to component segregation and interface weakening due to the addition of multiple components, making it difficult to effectively improve flexural strength. Traditional sintering aids cannot further improve flexural strength after achieving high density.

Method used

Using yttrium oxide as a sintering aid, combined with spark plasma sintering and heat treatment, residual compressive stress and dislocation network are introduced into the alumina matrix through the phase transformation reaction between yttrium oxide and alumina, and the volume expansion accompanying the phase transformation is used to improve the bending strength.

Benefits of technology

It significantly improves the flexural strength of alumina ceramics, reaching over 800 MPa, simplifies the raw material system and preparation process, and improves batch stability in industrial production.

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Abstract

本发明公开了一种基于可控相变制备高性能氧化铝陶瓷的方法及所得氧化铝陶瓷,属于陶瓷材料制备技术领域。本发明提供的方法包括:将氧化铝和氧化钇混合得到混合粉体,所述氧化钇占所述混合粉体总质量的2~5wt%;对所述混合粉体进行放电等离子烧结,烧结温度为1350~1550℃,得到第一陶瓷;将所述第一陶瓷在1100~1300℃的温度下热处理10~30 h,即得。本发明结合放电等离子烧结与后续热处理,利用相变伴随的体积膨胀在氧化铝基体内部产生残余压应力并诱发位错网络,从而在陶瓷达到高致密度后继续提升其抗弯强度,使制得的氧化铝陶瓷具有显著提高的抗弯强度,抗弯强度最高可达1100MPa以上。
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