一种阻燃抗菌聚氨酯材料及其制备方法

By combining KH560-SiO2@APP/MCA ternary synergistic composite flame retardant and PHMB-ZnO composite antibacterial agent with zinc borate and organomontmorillonite, the problems of flammability and insufficient antibacterial properties of polyurethane materials are solved, achieving efficient flame retardancy and long-lasting antibacterial effects, suitable for high-end application scenarios.

CN122213658BActive Publication Date: 2026-07-17DONGYING HAIRUIBAO NEW MATERIAL CO LTD +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
DONGYING HAIRUIBAO NEW MATERIAL CO LTD
Filing Date
2026-05-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Polyurethane materials have insufficient flammability and antibacterial properties, which limits their application in densely populated and medical environments. Furthermore, existing flame retardants and antibacterial agents are prone to decomposition during processing, affecting the stability of material performance.

Method used

By using KH560-SiO2@APP/MCA ternary synergistic composite flame retardant and PHMB-ZnO composite antibacterial agent, and through silane coupling agent modification and chemical bonding fixation, combined with zinc borate and organomontmorillonite, a multi-stage flame retardant and long-lasting antibacterial mechanism is formed, which solves the compatibility and stability problems of materials during processing.

Benefits of technology

It achieves highly efficient flame retardant and long-lasting antibacterial properties of polyurethane materials, maintains the mechanical properties of the materials, and avoids drug resistance and component loss through a single mechanism, meeting the safety and hygiene requirements of high-end application scenarios.

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Abstract

本发明公开了一种阻燃抗菌聚氨酯材料及其制备方法,涉及聚氨酯非金属增材用材料技术领域。该方法先制备KH560‑SiO2@APP / MCA复合阻燃剂:通过氢键自组装得到三聚氰胺氰尿酸盐,再使二氧化硅原位沉积于聚磷酸铵和该盐表面,最后接枝KH‑560;另以戊二醛为交联桥,将聚六亚甲基双胍共价锚定在氨基化纳米氧化锌表面,制得PHMB‑ZnO复合抗菌剂。将热塑性聚氨酯弹性体、上述阻燃剂和抗菌剂、硼酸锌、有机蒙脱土、抗氧化剂及润滑剂预混后,经熔融共混、挤出造粒、注塑成型,即得目标材料。本发明通过硼酸锌的化学缓冲与有机蒙脱土的物理隔离协同作用,有效抑制了加工过程中碱性胍基对聚磷酸铵的催化降解,使材料同时具备优异的阻燃性能和持久抗菌性能。
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