一种铝硅质大修渣的加速溶解处理方法

By ball milling and high-temperature residual electrode activation of aluminosilicate overhaul slag, combined with the synergistic effect of modified molten salt and cryolite-based electrolyte, the crystal lattice is destroyed and fluorides are released, solving the problem of slow dissolution rate of aluminosilicate overhaul slag, achieving efficient dissolution and high-silicon alloy production, and improving the stability of the electrolytic cell and waste heat utilization.

CN122214984BActive Publication Date: 2026-07-17ZHONGBEI UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
ZHONGBEI UNIV
Filing Date
2026-05-20
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing technologies, aluminum-silicon overhaul slag dissolves slowly in cryolite-based electrolytes, leading to a decrease in the concentration of metal oxides in the electrolyte, frequent occurrence of anodic effects, increased cell voltage, reduced current efficiency, and ineffective utilization of high-temperature residual heat, making it difficult to produce high-silicon alloys.

Method used

By pulverizing aluminosilicate overhaul slag using a ball mill and combining it with high-temperature residual electrode activation, the synergistic effect of modified molten salt and modified cryolite-based electrolyte is utilized to disrupt the dense crystal lattice, release internal fluorides, and generate easily soluble phases. Combined with mechanical activation and residual heat activation, the aluminosilicate overhaul slag is dissolved more quickly.

Benefits of technology

It significantly improves the dissolution rate of aluminum-silicon overhaul slag, produces high-silicon aluminum-silicon alloys with Si content of 4-15%, solves the problems of dissolution lag and furnace bottom sediment accumulation, realizes efficient utilization of residual heat, and maintains the stability of the electrolyte system.

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Abstract

本发明涉及溶解铝硅质大修渣技术领域,具体为一种铝硅质大修渣的加速溶解处理方法,包括以下步骤:S1.将铝硅质大修渣活化粉碎;S2.均匀铺展在耐热钢槽中,形成均匀薄层;S3.将高温残极平稳放置于平铺的大修渣微粉上方,周围添充大修渣微粉;S4.单次活化完成后,将其移至下一组新铺大修渣微粉上继续活化,依次循环,直至残极温度降至400℃以下,停止活化,收集所有经活化处理的大修渣;S5.将经活化处理的大修渣加入铝电解槽的改性冰晶石基电解质中,完成铝硅质大修渣的加速溶解。本发明提出机械活化与余热活化双重强化,破坏致密晶格、释放内部氟化物、生成易溶物相,使得铝硅质大修渣溶解速率得到显著提升,能够生产Si含量在4‑15%的高硅铝硅合金。
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