一种莫来石微晶玻璃及其制备方法

By combining ion exchange, deammoniation treatment, and pre-collapse heat treatment with the SPS process, and controlling the sodium-aluminum molar ratio, low-temperature and short-time preparation of mullite glass-ceramics was achieved. This solved the problem of synergistic optimization of transparency and mechanical properties, and improved the transparency and mechanical properties of mullite glass-ceramics.

CN122233660BActive Publication Date: 2026-07-17DONGHUA UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
DONGHUA UNIV
Filing Date
2026-05-14
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies cannot achieve synergistic optimization of transparency and mechanical properties of mullite glass within a low-temperature, short-time process window. Traditional preparation methods lead to grain coarsening, enhanced light scattering, and residual stress, resulting in a decline in material reliability and mechanical properties.

Method used

Using molecular sieve precursors as raw materials, the degassing and densification processes are decoupled by controlling the sodium-aluminum molar ratio within the range of 0.15-0.60 through ion exchange, deammoniation treatment and pre-collapse heat treatment, combined with the SPS process, to promote the uniform precipitation of nano-mullite crystals and form a nanocrystalline-residual glass complex structure.

Benefits of technology

Achieving synergistic optimization of high transparency and high mechanical properties of mullite microcrystalline glass under low temperature and short-time conditions, significantly reducing residual porosity and scattering defects, and improving hardness, fracture toughness and elastic modulus.

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Abstract

本发明属于微晶玻璃材料技术领域,涉及一种莫来石微晶玻璃及其制备方法。制备方法以分子筛前驱体为原料,分子筛前驱体为纳米FAU Y分子筛,包括离子交换工序、脱铵处理工序、预坍塌热处理工序和SPS工序,离子交换即用NH4+替换纳米FAU Y分子筛中的Na+;脱铵处理即脱除包含NH3在内的挥发组分;预坍塌热处理的目的是使微孔特征基本消失、比表面积降低并减少挥发组分滞留。所述莫来石微晶玻璃兼具高透明度与高力学性能。本发明可在低温、短时工艺窗口内协同调控结构演化,适配显示基板、先进封装等对光学与机械性能有双重严苛要求的应用场景。
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