一种耐刮擦水性油墨及其制备方法

By designing a multi-layer core-shell grafted hybrid emulsion, the problem of scratches and abrasions caused by water-based inks during the printing process is solved, achieving high scratch resistance and surface slip characteristics of the film layer, and improving the scratch resistance and anti-scratch ability of printed materials.

CN122234654BActive Publication Date: 2026-07-17山东布瑞特油墨有限公司 +4

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
山东布瑞特油墨有限公司
Filing Date
2026-05-25
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing water-based inks are prone to scratches, abrasions, and uneven gloss during the printing process. Their scratch resistance is difficult to balance the brittleness and toughness of the film layer, and the uneven distribution of the slip component makes the surface susceptible to mechanical friction damage.

Method used

A multilayer core-shell grafted hybrid emulsion is used as the film-forming resin, including a polyurethane core layer, an acrylic intermediate layer containing diacetone acrylamide, and an acrylic outer layer containing reactive organosilicon macromonomers. It is combined with an oxazoline copolymer solution and a diacylhydrazine crosslinking system to form a covalent grafted structure and crosslinking network, thereby improving the film density and slip characteristics.

Benefits of technology

This technology enables water-based inks to maintain good toughness while improving surface slip characteristics and scratch resistance, reducing the probability of scratch formation, and enhancing the scratch resistance of the film.

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Abstract

本发明属于油墨制备技术领域,提供了一种耐刮擦水性油墨及其制备方法。所述油墨包括颜料、成膜树脂乳液、含噁唑啉基团的水溶性共聚物溶液、二酰肼交联剂、分散剂、助溶剂、润湿剂、消泡剂、流平剂、非离子聚氨酯缔合型增稠剂、胺调节剂及水;所述成膜树脂乳液为多层核壳接枝型杂化乳液;制备方法包括:由聚碳酸酯二醇、聚二甲基硅氧烷醇、脂肪族二异氰酸酯、含羧基二醇、羟基丙烯酸酯与扩链剂制得聚氨酯预聚体,经中和水分散并扩链,脱除溶剂得到聚氨酯分散体;在过硫酸铵引发下分段种子乳液聚合形成中间层与外层;研磨分散颜料后与树脂乳液调墨,并顺序加入各助剂与交联剂,调节酸碱度并加入噁唑啉共聚物溶液得到成品。
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