一种基于薄液膜电极的燃料电池离聚物评价方法及应用

By constructing a thin liquid film electrode in a fuel cell, the problem of evaluating the three-phase interface construction and hydration control of ionomers under actual operating conditions in the prior art is solved. This enables independent and quantitative evaluation of ionomer performance and improves the controllability and representativeness of the test.

CN122259684BActive Publication Date: 2026-07-17CHONGQING UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CHONGQING UNIV
Filing Date
2026-05-27
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies are insufficient to effectively evaluate the three-phase interface construction ability, local hydration state regulation effect, and intrinsic ion conduction characteristics of ionomers in actual membrane electrode catalytic layers in fuel cells. Most existing methods are conducted under ideal conditions, which cannot reflect the film-forming ability and interface construction ability of ionomers under actual operating conditions.

Method used

An evaluation method based on thin liquid film electrodes is adopted. A thin liquid film is constructed on the surface of the working electrode to form a gas-liquid-solid three-phase interface. Electrochemical tests are then performed to evaluate the performance of the ionomer. This includes dispersing the catalyst and the ionomer to be tested to form an electrode slurry, assembling the working electrode, constructing the thin liquid film, and performing electrochemical tests.

Benefits of technology

This enables independent and quantitative evaluation of the three-phase interface construction ability, hydration regulation ability and ion conduction performance of ionomers under near-real-world conditions, reducing the influence of coupling factors and improving the representativeness and controllability of the test.

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Abstract

本发明公开了一种基于薄液膜电极的燃料电池离聚物评价方法及应用,属于汽车燃料电池技术领域。本发明中的方法先将催化剂和待测离聚物分散于溶剂中形成电极浆料,涂布至气体扩散层表面形成气体扩散电极;再将气体扩散电极与密封垫片及石墨流场板组装成工作电极并固定于电解池中;向电解池中加入电解液,采用提拉法或蒸汽润湿法在工作电极的催化层表面构建连续均匀的薄液膜,形成气‑液‑固三相界面;通入反应气体进行电化学测试,根据测试结果评价离聚物性能。本发明通过构建薄液膜电极,模拟真实燃料电池催化层中的三相界面环境,实现了离聚物本征性能与三相界面构筑效果的解耦评价,可应用于燃料电池离聚物筛选。
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