Titanium alloy surface titania nanotube-polyvinylidene fluoride piezoelectric composite layer, preparation method and application thereof

By preparing a titanium dioxide nanotube-polyvinylidene fluoride piezoelectric composite layer on the surface of titanium alloy, the problems of antibacterial properties and energy dissipation of titanium alloy implants were solved, improving the osteogenic, antibacterial and stability properties of the implants, and achieving multifunctional modification.

CN122399100APending Publication Date: 2026-07-17LANZHOU UNIV
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
LANZHOU UNIV
Filing Date
2026-02-13
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing titanium alloy implants have weak antibacterial properties, making them susceptible to infection. They also lack energy dissipation capabilities, resulting in poor implant stability, especially when subjected to overload, which can easily lead to bone resorption.

Method used

A titanium dioxide nanotube-polyvinylidene fluoride (PVDF) piezoelectric composite layer was prepared on the surface of a titanium alloy. Titanium dioxide nanotubes were formed as a transition layer by secondary anodic oxidation, and then a PVDF layer was cast. The piezoelectric properties were enhanced by corona polarization. The viscoelasticity and piezoelectric effect of PVDF were utilized to promote osteogenic and antibacterial properties.

Benefits of technology

It improves the implant's osteogenic capacity, antibacterial properties, energy dissipation performance, and biocompatibility, enhances the implant's long-term stability and resistance to infection, reduces stress concentration, and promotes osseointegration.

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Abstract

本发明公开了钛合金表面二氧化钛纳米管‑聚偏氟乙烯压电复合层及其制备方法和应用。通过二次阳极氧化法在钛合金表面制备二氧化钛纳米管作为过渡层,再在二氧化钛纳米管层上浇铸聚偏氟乙烯层,增加聚偏氟乙烯与钛合金基底的结合。同时通过电晕极化将聚偏氟乙烯中极性β相相对含量增加,增强压电性能,利用聚偏氟乙烯本身粘弹性,增强钛合金种植体的能量耗散性能;通过外部施加超声,促进PVDF通过压电效应产生周围局部电势,提高成骨、抗菌性能。该二氧化钛纳米管‑聚偏氟乙烯压电复合层改性的钛合金种植体,能够作为一种新型的多功能改性方式应用于钛合金种植体中,提高种植体的长期稳定性,解决目前种植体抗菌性弱和负荷过载引起骨吸收的问题。
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