Process for improving the effect of limestone-gypsum method for removing ultra-high sulfur flue gas

By improving the slurry formulation and zone control of the limestone-gypsum process, and combining it with a crystallization modifier, the problems of low desulfurizing agent utilization and poor gypsum quality in ultra-high sulfur flue gas desulfurization were solved, achieving efficient and low-cost desulfurization and gypsum resource utilization.

CN122399531APending Publication Date: 2026-07-17铜陵有色金属集团股份有限公司

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
铜陵有色金属集团股份有限公司
Filing Date
2026-05-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The limestone-gypsum method for treating ultra-high sulfur flue gas suffers from problems such as low desulfurization agent utilization, easy scaling and clogging of the system, and poor gypsum quality, making it difficult to meet the requirements of efficient desulfurization and resource utilization.

Method used

By adjusting the limestone slurry formula, controlling the pH value and the amount of oxidizing air in different zones, and combining sodium citrate and sodium polyacrylate as crystallization modifiers, the gypsum crystal morphology is optimized, and solid-liquid separation is carried out in a vacuum belt dewatering machine to improve the utilization rate of limestone slurry and the quality of gypsum.

Benefits of technology

It achieves high desulfurization efficiency (≥99%), stable SO2 concentration at the outlet, high gypsum purity (≥93%), and low moisture content (≤12%), thereby reducing operating costs and equipment wear and extending maintenance cycles.

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Abstract

本发明公开了一种改善石灰石‑石膏法脱除超高硫烟气效果的工艺方法,包括以下步骤:S1、石灰石浆液制备:将石灰石粉和生石灰粉按一定比例混合,要求粒度‑325目≥95%,同时添加一定的结晶改良剂,配制25wt%~30wt%的浆液;S2、循环吸收:浆液输入吸收塔,通过外置储槽,将吸收塔划分为上部喷淋吸收区、下部喷淋吸收区和底部浆池氧化结晶区,实现分区独立控制;S3、氧化风系统:将吸收塔内的氧化空气量相对按入口SO2摩尔流率算的理论需氧量的倍数控制在合理范围内;S4、脱硫石膏脱水:在吸收塔内生成的脱硫石膏浆液先进入石膏旋流器进行预浓缩,再送入真空皮带脱水机进行固液分离。本发明的有益效果是提升了进口烟气中二氧化硫浓度≥10000mg / Nm³的脱硫效果。
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