间苯二胺与铜离子配位调节的纳滤膜及其制备方法和应用

The nanofiltration membrane preparation method using the coordination regulation of m-phenylenediamine and copper ions solves the problem of balancing water flux and retention rate in polyamide nanofiltration membranes, achieving high-efficiency separation performance and stable membrane structure, and simplifying the preparation process.

CN122399591APending Publication Date: 2026-07-17ANHUI PUSHI ECOLOGICAL ENVIRONMENT ENG

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
ANHUI PUSHI ECOLOGICAL ENVIRONMENT ENG
Filing Date
2026-05-26
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing polyamide nanofiltration membranes struggle to balance water flux and ion retention performance, and existing modification methods are complex and lack sufficient stability in copper ion fixation, leading to unstable membrane structures.

Method used

A nanofiltration membrane preparation method using coordination regulation of m-phenylenediamine and copper ions was adopted. The polymer support layer was treated with an aqueous solution containing piperazine, and then contacted with an aqueous solution containing m-phenylenediamine and copper ions to form a coordination effect. The membrane was then subjected to interfacial polymerization with polyacrylamide monomers to prepare a stable polyamide selective layer.

Benefits of technology

This method improves the water flux of nanofiltration membranes while maintaining good divalent ion rejection performance, simplifies the preparation process, and enhances the stability of the membrane structure and separation efficiency.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure CN122399591A_ABST
    Figure CN122399591A_ABST
Patent Text Reader

Abstract

本发明属于水处理膜材料技术领域,具体涉及一种间苯二胺与铜离子配位调节的纳滤膜及其制备方法和应用。所述制备方法包括:将高分子支撑层与含哌嗪的水相溶液接触,得到第一改性膜;将第一改性膜与含间苯二胺和铜离子的水相溶液接触,得到第二改性膜;将第二改性膜与含多元酰氯单体的有机相溶液接触,使第二改性膜表面的胺类单体与多元酰氯单体发生界面聚合反应,得到第三改性膜;将第三改性膜进行水处理,得到所述纳滤膜。本发明通过间苯二胺与铜离子的配位作用调节界面聚合反应,有利于改善聚酰胺选择层结构,提高纳滤膜水通量,并保持较好的离子截留能力。所述纳滤膜可用于盐水中一价盐离子和二价盐离子的分离、工业废水处理或海水淡化预处理。
Need to check novelty before this filing date? Find Prior Art