一种正渗透膜及其制备方法和应用

By introducing an EVOH-GA intermediate layer into the forward osmosis membrane, the stability and lifespan issues of traditional forward osmosis membranes in acidic environments were solved, resulting in a forward osmosis membrane with excellent acid resistance, which improved water flux and ion rejection rate.

CN122399592APending Publication Date: 2026-07-17TIANJIN JUYI CONSTR ENG CO LTD +1
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
TIANJIN JUYI CONSTR ENG CO LTD
Filing Date
2026-06-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing forward osmosis membranes have poor stability and short service life in acidic environments, making it difficult to meet the needs of acidic wastewater treatment in the phosphorus chemical industry.

Method used

A hydrophilic intermediate layer formed by crosslinking ethylene-vinyl alcohol copolymer and glutaraldehyde is introduced between the base membrane layer and the separation layer. A stable chemical crosslinking structure is formed through interfacial polymerization, thus preparing a forward osmosis membrane with high selectivity, high water permeability and excellent acid resistance.

Benefits of technology

It significantly improves the structural stability and acid resistance of the membrane, effectively avoids interlayer delamination and hydrolysis problems, increases water flux and ion rejection rate, and extends the service life of the membrane.

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Abstract

本发明公开了一种正渗透膜及其制备方法和应用,一种正渗透膜,包括依次叠加设置的基膜层、中间层和分离层;基膜层包括含羟基的多孔亲水聚乙烯膜;中间层包括乙烯‑乙烯醇共聚物与戊二醛交联反应形成的亲水层,中间层锚定于所述基膜层表面并渗入所述基膜层的孔隙中;由单体混合物聚合形成的含氟聚磺酰胺,所述单体混合物包括多元胺单体和多元磺酰氯单体,多元胺单体中包括不含氟多元胺单体和含氟刚性胺单体。本发明对基膜层进行表面改性,在赋予其高亲水性的同时,有效调控了基膜层表面的孔径大小,成功制备出一种兼具高选择性、高透水性、尤其是耐酸性优异的正渗透膜。
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